Browsing by Author "Rocha, J."
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- Blistering of W-Ta composites at different irradiation energiesPublication . Mateus, R.; Dias, M.; Lopes, J.; Rocha, J.; Catarino, N.; Duarte, P.; Gomes, R. B.; Silva, C.; Fernandes, H.; Livramento, V.; Carvalho, P. A.; Alves, E.; Hanada, K.; Correia, J. B.Pure tungsten and tantalum plates and tungsten-tantalum composites produced via mechanical alloying and spark plasma sintering were bombarded with He+ and D+ energetic ion beams and deuterium plasmas. The aim of this experiment is to study the effects caused by individual helium and deuterium exposures and to evidence that the modifications induced in the composites at different irradiation energies could be followed by irradiating the pristine constituent elements under the same experimental conditions, which is relevant considering the development of tailored composites for fusion applications. Higher D retentions, especially in tungsten, and superficial blistering are observed in both components after helium exposure. The blistering is magnified in the tantalum phase of composites due to its higher ductility and to water vapour production under deuterium irradiation. At lower irradiation energies the induced effects are minor. After plasma exposure, the presence of tantalum does not increase the D content in the composites. (C) 2013 Elsevier B.V. All rights reserved.
- Catalytic behavior of alkali-treated Pt/HMOR n-hexane hydroisomerizationPublication . Monteiro, R.; Ania, Conchi O.; Rocha, J.; Carvalho, A. P.; Martins, Ângela Maria PereiraBifunctional Pt-HMOR catalysts were prepared by incipient wetness impregnation of various desilicated MOR obtained by alkaline treatment using NaOH concentrations ranging from 0.1 to 0.5 M. The zeolite structural changes upon modification were investigated by several techniques including powder X-ray diffraction,Al-27 and Si-29 MAS-NMR spectroscopy, N-2 adsorption, pyridine adsorption followed by infrared spectroscopy and the catalytic model reaction of m-xylene transformation. For low alkaline concentration the zeolite acidity is preserved, along with a slight increase of the volume correspondent to the larger micropores due to the removal of extra-framework debris already existent at the parent zeolite. At higher NaOH concentrations there is a significant loss of crystalinity and acidity as well as the formation of mesoporosity. The characterization of the metal function shows similar patterns for Pt-HMOR and Pt-M/0.1 samples, with Pt particles located mainly inside the inner porosity. In contrast, large Pt particles become visible at the intercrystalline mesoporosity of MOR crystals developed during the desilication treatments at severe alkaline conditions. The catalytic results obtained for n-hexane hydroisomerization showed an improved selectivity for dibranched over monobranched isomers for Pt-M/0.1 sample, likely due to the preservation of the support acidity and the slight enlargement of the micropores. This work is a new example in which the mesoporous development does not improve the catalytic efficiency of the zeolites, whereas mild alkaline desilication might be considered as an effective solution to produce customized catalysts with enhanced performance for a given application. (C) 2014 Elsevier B.V. All rights reserved.
- Characterization of a single electrode focusing lens for ion beam decelerationPublication . Lopes, Jose; Rocha, J.; Catarino, Norberto; Redondo, LuisAn ion beam deceleration system was studied for the highcurrent ion implanter at the Laboratório de Aceleradores e Tecnologias de Radiação at the Campus Tecnológico e Nuclear, of Instituto Superior Técnico. The installed system consists of a target plate and one electrostatic focusing lens with one electrode. This article describes the results of the evaluation of the new system. With this upgrade, the ion implanter provides enhanced versatility for decelerating to 5 keV a high current ion beam at the µA level. This implantation provides a wide area and allows for a continuous magnetic beam scanning, extending the energy range to lower values, opening up a wider set of applications.
- Desilication of MOR zeolite: Conventional versus microwave assisted heatingPublication . Paixão, V.; Monteiro, R.; Andrade, M.; Fernandes, A.; Rocha, J.; Carvalho, A. P.; Martins, A.MOR zeolites were modified via desilication treatments with NaOH, under conventional and microwave heating. The samples were characterized by powder X-ray diffraction, (27)Al and (29)Si NMR spectroscopy. TEM and N(2) adsorption at -196 degrees C. The acidity of the samples and the space available inside the pores were evaluated through a catalytic model reaction, the isomerization of m-xylene, for which the profiles of the coke thermal decomposition were also analyzed. Powder X-ray diffraction and (29)Si and (27)Al MNR results show that in comparison with conventional heating, microwave irradiation (a less time consuming process) leads to identical amount of Si extraction from the zeolite framework. With this treatment. in addition to the customary mesopores development promoted by conventional heating, a partial conversion of the zeolite microporosity into larger micropores, is observed. The microwave irradiated and conventionally heated samples show different catalytic behavior in the m-xylene isomerization model reaction. It was observed that, by controlling the experimental conditions, it is possible to obtain samples with catalytic properties closer to the parent material, which is also confirmed by the respective coke analysis. (C) 2011 Elsevier B.V. All rights reserved.
- Ion beam monitoring over a biased targetPublication . Lopes, J. Gabriel; Rocha, J.; Catarino, N.; Peres, M.A specially designed beam profile monitor (BPM) was produced to be assembled over a biased target plate, with the aim of studying the effect of an ion beam deceleration system on the beam fluence due to beam dispersion. The new BPM was developed with a shape as flat as possible, so it could be attached to a biased target plate without affecting the target geometry, using a slit scan method to produce an high-resolution beam profile. This system was designed and installed on the high current ion implanter at the Laboratorio de Aceleradores e Tecnologias de Radiacao, at the Campus Tecnologico e Nuclear, of Instituto Superior Tecnico, in Lisbon. The system is capable of showing the ion beam profile for low-energy ion beams below 15 keV, using a beam deceleration system.
- Mass spectrometry improvement on an high current ion implanterPublication . Lopes, J. Gabriel; Alegria, F. C.; Luis Redondo; Rocha, J.; Alves, E.The development of accurate mass spectrometry, enabling the identification of all the ions extracted from the ion source in a high current implanter is described. The spectrometry system uses two signals (x-y graphic), one proportional to the magnetic field (x-axes), taken from the high-voltage potential with an optic fiber system, and the other proportional to the beam current intensity (y-axes), taken from a beam-stop. The ion beam mass register in a mass spectrum of all the elements magnetically analyzed with the same radius and defined by a pair of analyzing slits as a function of their beam intensity is presented. The developed system uses a PC to control the displaying of the extracted beam mass spectrum, and also recording of all data acquired for posterior analysis. The operator uses a LabView code that enables the interfacing between an I/O board and the ion implanter. The experimental results from an ion implantation experiment are shown. (C) 2011 Elsevier B.V. All rights reserved.
- Modifications of MCM-22 zeolite through sequential post-synthesis treatments. Implications on the acidic and catalytic behaviourPublication . Machado, V.; Rocha, J.; Carvalho, A. P.; Martins, A.Desilication and a combination of alkaline followed by acid treatment were applied to MCM-22 zeolite using two different base concentrations. The samples were characterised by powder X-ray diffraction, Al-27 and Si-29 MAS-NMR spectroscopy, SEM, TEM and low temperature N-2 adsorption. The acidity of the samples was study through pyridine adsorption followed by FTIR spectroscopy and by the analyses of the hydroxyl region. The catalytic behaviour, anticipated by the effect of post-synthesis treatments on the acidity and space available inside the two internal pore systems was evaluated by using the model reaction of m-xylene transformation. The generation of mesoporosity was achieved upon alkaline treatment with 0.05 M NaOH solution and practically no additional gain was obtained when the more concentrate solution, 0.1 M, was used. Instead, Al extraction takes place along with Si, as shown by Si-29 and Al-27 MAS-NMR data, followed by Al deposition as extraframework species. Samples submitted to alkaline plus acid treatments present distinct behaviour. When the lowest NaOH solution was used no relevant effect was observed on the textural characteristics. Additionally, when the acid treatment was performed on an already fragilized MCM-22 structure, due to previous desilication with 0.1 M NaOH solution, the extraction of Al from both internal pore systems promotes their interconnection, evolving from a 2-D to a 3-D porous structure. This transformation has a marked effect in the catalytic behaviour, allowing an increase of m-xylene conversion as a consequence of an easier and faster molecular traffic in the 3-D structure. On the other hand, the continuous deposition of extraframework Al species inside the pores leads to a shape selective effect that privileges the formation of the more valuable isomer p-xylene.
- Registador de dados para aplicações de baixo consumoPublication . Casaleiro, João; Rocha, J.; Reis, R.; Pinto, A.; Oliveira, T.; Gomes, M.; Fazenda, P.; Costa, V.; Carvalho, C.Este artigo descreve uma arquitectura de um registador de dados para aplicações de baixo consumo. São apresentados resultados experimentais sobre o desempenho do oscilador, que é um dos módulos do registador. São ainda apresentadas estimativas do consumo do registador e dos respectivos módulos. A autonomia e a estabilidade são os critérios de projecto mais relevantes de um registador de dados para aplicações de baixo consumo que exijam precisão temporal, por exemplo a sismologia oceânica.
- Simple general purpose ion beam deceleration system using a single electrode lensPublication . Lopes, J.; Rocha, J.Ion beam deceleration properties of a newly developed low-energy ion beam implantation system were studied. The objective of this system was to produce general purpose low-energy (5 to 15 keV) implantations with high current beam of hundreds of μA level, providing the most wide implantation area possible and allowing continuously magnetic scanning of the beam over the sample(s). This paper describes the developed system installed in the high-current ion implanter at the Laboratory of Accelerators and Radiation Technologies of the Nuclear and Technological Campus, Sacavém, Portugal (CTN).
- Sistema electrónico de controlo de temperatura da água para aplicações domésticasPublication . Oliveira, T.; Reis, R.; Casaleiro, João; Fazenda, P.; Ramos, H.; Pinto, A.; Gomes, M.; Rocha, J.Este artigo descreve um sistema que permite controlar a temperatura e regular o caudal das águas sanitárias num ambiente doméstico. O sistema tem como limite sete saídas independentes de caudal, substituindo as tradicionais torneiras mecânicas e manuais. A arquitectura do sistema está dividida em dois tipos de blocos: a interface com o utilizador (IU) e o bloco de controlo e regulação (CR). A IU é composta por um mostrador e por um teclado que permitem a interacção do utilizador com o sistema. O bloco de CR é constituído por um circuito electrónico que gere os módulos da IU e o sistema electromecânico. No controlo de temperatura é usado um controlador PID digital. A regulação do caudal de cada saída é efectuada de forma independente.