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- Thermal performance of concrete with reactive magnesium oxide as an alternative binderPublication . Forero Valencia, Javier Andres; Bravo, Miguel; Pacheco, João; Brito, Jorge de; Evangelista, LuisThis study evaluates the thermal conductivity of concrete produced with reactive magnesium oxide (MgO) as a partial replacement for cement. MgO is a viable option for the concrete industry, mainly due to its benefits in sustainability and reducing CO2 emissions compared to cement emissions. Four different MgO's produced in Australia, Canada, and Spain were used in concrete mixes as a partial replacement of cement at 5%, 10%, and 20% by mass. The experimental results showed that the thermal conductivity is higher when MgO increases in mixes after 28 days of curing. With the incorporation of MgO, the thermal conductivity increased between 3.2% and 10.2%, and the mechanical properties declined: compressive strength between 12.7% to 26.2%, splitting tensile strength between 9.7% to 34.0%, and modulus of elasticity between -4.1% to 7.8%. Finally, it is important to highlight that the addition of different contents of MgO in the concrete mixes modified the microstructure of the cement matrix. As a result, there was an increase in porosity, which negatively influenced the mechanical properties and thermal conductivity. Therefore, the relationships between these properties were also analyzed.
- High-performance self-compacting concrete with recycled aggregates from the precast industry: durability assessmentPublication . Barroqueiro, Tiago; Raposeiro Da Silva, Pedro; De Brito, JorgeThe main objective of this paper is to provide the industry with a simple and practical way of disposing and recovering recycled waste from precast reinforced concrete elements rejected during the quality control process, while minimizing the consumption of natural resources in the production of concrete and, consequently, significantly reducing the environmental impact of both (construction and demolition waste and extracting natural aggregates). In other words, with this work, the intention is to evaluate the feasibility of producing high-performance self-compacting concrete with a less environmental impact, by replacing natural aggregates (NA) with fine and coarse recycled aggregates resulting from the precast industry, which allows the future use of this type of aggregates in the industrial process without reservations concerning the expected durability performance. To achieve these objectives, six types of self-compacting concrete (SCC) were produced incorporating diferente amounts of recycled aggregates. Six replacement ratios for fine recycled aggregates (FRA) and coarse recycled aggregates (CRA) were considered: (FRA/CRA) 0/0; 25/25; 50/50; 100/100; 0/100 and 100/0%. Six di_erent tests were carried out to characterize both the main concrete transport mechanisms and the main concrete degradation mechanisms, namely: the immersion water absorption test, capillary water absorption test, oxygen permeability test, chloride migration test, electrical resistivity test and carbonation test. The obtained results clearly demonstrate that, despite the negative influence of the inclusion of recycled aggregates, it is still possible to produce high-performance self-compacting concrete with perfectly acceptable durability properties.
- On the development of a technical specification for the use of fine recycled aggregates from construction and demolition waste in concrete productionPublication . Bravo, Miguel; Duarte, António P. C.; De Brito, Jorge; Evangelista, Luís; Pedro, DiogoThe possibility of using recycled aggregates from construction and demolition waste (CDW) in concrete is rather widely agreed upon when it comes to the use of coarse recycled aggregates. However, this is not the case when fine recycled aggregates (FRA) are considered, as it is deemed that these seriously impair the behaviour of concrete. Hence, this work presents a technical specification proposal for the use of FRA from CDW in concrete, to attempt to fill this gap in legislation. The specification is based on a wide collection of experimental results, from which it is shown that for low incorporation ratios (up to 25%), the properties of concrete with FRA from CDW are comparable to those of a reference concrete. The intended international scope of the specification is ensured by the fact that FRA from CDW are typified by composition (percentage of concrete, masonry, glass, etc.) rather than by geographical origin or construction type. It is shown that, after typifying the FRA and assuming, as per design, the acceptable percentage losses (relative to a reference concrete) of mechanical, durability-related and long-term physical properties, if the maximum incorporation ratios proposed of each type of FRA are used, the variation of properties remains within the limits established.
- Eurocode shear design of coarse recycled aggregate concrete: reliability analysis and partial factor calibrationPublication . Pacheco, João; Brito, Jorge de; Chastre, Carlos; Evangelista, LuisThis paper contributes to the definition of design clauses for coarse recycled aggregate concrete. One of the main reasons for scepticism towards recycled aggregate concrete is the perceived notion that the heterogeneity of recycled aggregates may increase the uncertainty of the behaviour of concrete. Therefore, the paper uses structural reliability concepts to propose partial factors for recycled aggregate concrete's design for shear failure. The paper builds upon a previous publication by the authors, in which the model uncertainty of recycled aggregate concrete elements designed for shear, with and without shear reinforcement, was compared with that of natural aggregate concrete elements. In that paper, the statistics of the model uncertainty for recycled aggregate concrete shear design were indeed found to be less favourable than those of natural aggregate concrete. Therefore, a partial factor for recycled aggregate concrete design is needed to ensure safety. This paper presents partial factors calibrated with explicit reliability analyses for different cases of design concerning beams (in the case of shear design of elements with shear reinforcement) and slabs (for the design of elements without shear reinforcement). For full incorporation of coarse recycled concrete aggregates and the design of elements without shear reinforcement, the calibrated partial factor reduces the design value of shear resistance by 10% (design with EN1992) or 15% (design with prEN1992) in comparison to natural aggregate concrete's design. For the shear design of elements with shear reinforcement, the partial factor decreases resistance by 5% but a sensitivity analysis showed that the reduction might be, under pessimistic expectations, of up to 20%.
- Magnesia (MgO) production and characterization, and its influence on the performance of cementitious materials: a reviewPublication . Nobre, José; Hawreen, Ahmed; Bravo, Miguel; Evangelista, Luis; De Brito, JorgeThis paper presents a literature review concerning the characteristics of MgO (magnesium oxide or magnesia) and its application in cementitious materials. It starts with the characterization of MgO in terms of production processes, calcination temperatures, reactivity, and physical properties. Relationships between different MgO characteristics are established. Then, the influence of MgO incorporation on the properties of cementitious materials is investigated. The mechanical strength and durability behaviour of cement pastes, mortars and concrete mixes made with MgO are discussed. The studied properties of MgO-cement mixes include compressive strength, flexural strength, tensile strength, modulus of elasticity, water absorption, porosity, carbonation, chloride ion penetration, shrinkage, expansion, and hydration degree. In addition, microscopic analyses of MgO-cement mixes are also assessed. Summarizing the results of different studies, it is concluded that MgO incorporation in cementitious materials generally decreases the mechanical strength and shrinkage, and increases the porosity, expansion, carbonation and chloride ion migration. However, it should be emphasized that the properties of the specific MgO used (mainly the calcination temperature, the reactivity and the surface area) have a significant influence on the characteristics of the cementitious materials produced.
- Bond of recycled coarse aggregate concrete: model uncertainty and reliability-based calibration of design equationsPublication . Pacheco, João; Brito, Jorge de; Chastre, Carlos; Evangelista, LuisThis paper concerns the design of lap splice lengths for ribbed steel reinforcement bars embedded in concrete produced with coarse recycled concrete aggregates. Recycled aggregates are weaker and typically lead to concrete with lower tensile strength. Both aspects change the model uncertainty of bond strength formulae and a major topic of the paper is the influence of recycled aggregates on the model uncertainty of the bond strength model of fib Bulletin 72. A stochastic model for this model uncertainty is developed from a meta-analysis. The model uncertainty, estimated from analogue specimens made with either natural aggregate concrete or recycled aggregate concrete, is compared and the incorporation of recycled aggregates was indeed found to have a detrimental influence on the model uncertainty. A partial factor for lap splice length design is calibrated through reliability analyses so that the probability of failure of the bond length design of recycled aggregate concrete is equivalent to that of natural aggregate concrete. Two design equations were studied: that of the fib Bulletin 72 and that of the D6 draft of the second generation of Eurocode 2.
- Ternary blends for self-compacting mortars production composed by electric arc furnace dust and other industrial by-productsPublication . Lopez-Uceda, Antonio; Cantador, David; Raposeiro Da Silva, Pedro; De Brito, Jorge; Fernandez Rodriguez, Jose Maria; Jimenez, Jose RamonThis study is framed within the circular economy model through the valorisation of industrial by-products. This research shows the results of producing self-compacting mortars (SCMs) with electric arc furnace dust (EAFD) and other industrial by-products such as fly ash, conforming (FA) or not conforming (NcFA), from coal-fired power plants, or recovery filler (RF) from hot-mix asphalt plants. Three batches of SCMs, each with one industrial-by product (FA, NcFA, or RF), and three levels of EAFD ratio incorporation (0%, 10%, 20%), were tested. An extra batch with a greater amount of FA was manufactured. When the incorporation ratio of EAFD rose, the mechanical strength decreased, due to the presence of a calcium zinc hydroxide dihydrate phase; nevertheless, this decrease diminished over time. All SCM mixes, except the 40C 40FA 20 EAFD mix, were above 20 MPa at 28 days. All mixes named 70C and 40C reached 40 and 30 MPa, respectively, at 90 days. Mixes with EAFD showed less capillarity and no difference in water absorption by immersion with respect to mixes without EAFD after 91 days. The SCMs designed proved to be stable in terms of leaching of the heavy metals contained in EAFD, where all the hardened SCMs were classified as inert.
- Fracture behaviour of concrete with reactive magnesium oxide as alternative binderPublication . Forero, J. A.; Bravo, M.; Pacheco, João; De Brito, Jorge; Evangelista, LuisThis research evaluates the fracture behavior of concrete with reactive magnesium oxide (MgO). Replacing cement with MgO is an attractive option for the concrete industry, mainly due to sustainability benefits and reduction of shrinkage. Four different MgO's from Australia, Canada, and Spain were used in the concrete mixes, as a partial substitute of cement, at 5%, 10%, and 20% (by weight). The fracture toughness (K-I) intensity factor and the stress-strain softening parameters of the wedge split test were evaluated after 28 days. The experimental results showed that the replacement of cement with MgO reduced the fracture energy between 13% and 53%. Moreover, the fracture energy was found to be correlated with both compressive strength and modulus of elasticity. A well-defined relationship between these properties is important for an adequate prediction of the non-linear behavior of reinforced concrete structures made with partial replacement of cement with MgO.
- Improvement of the quality of recycled concrete aggregate subjected to chemical treatments: a reviewPublication . Forero, Javier A.; De Brito, Jorge; Evangelista, Luis; Pereira, CláudioThe main factor that alters the quality of recycled concrete aggregate (RCA) is the paste adhered to the natural aggregate (NA). Since it causes weakening of the interfacial transition zone (ITZ) between the aggregate and the cementitious paste, it becomes a determining factor for the mechanical behavior of concrete. It turns out that it is critical to enhance this interface by improving the surface of the aggregate or by removing the paste adhered to the NA. Considering the variety of methods for removing paste adhered to RCA-namely using acids such as hydrochloric acid (HCl), sulfuric acid (H2SO4), and phosphoric acid (H3PO4), among others-this paper presents a review of treatments for the removal of adhered paste using acidic solutions on the RCA, and their influence on the mechanical properties and durability of concrete produced with RCA. Pearson's correlation was used in the statistical analysis to determine the linear relationship of the main factors-for instance, immersion time, acidic solution, and aggregate size-involved in the removal of the paste in the RCA.
- Durability and shrinkage performance of concrete made with coarse multi-recycled concrete aggregatesPublication . Silva, Stefano; Evangelista, Luis; De Brito, JorgeSince construction is one of the most environmental impacting activities in existence, it is important to study and develop solutions to make its processes more efficient. Thus, multiple-recycling of concrete presents itself as a possible alternative for the reutilization of construction and demolition waste (CDW) over a large period of time. This paper presents the results and conclusions obtained from an extensive experimental campaign intended to study the durability performance of concrete made with aggregates resulting from multiple recycling cycles. Concrete mixes with 25% and 100% of substitution of natural coarse aggregates with recycled coarse concrete aggregates obtained from one, two and three recycling cycles were produced. Tests such as sieve analysis, water absorption, particle density, shape index, particle bulk density and Los Angeles abrasion were made to study the recycled coarse aggregates properties. Additionally, the workability and bulk density of fresh concrete were measured, and water absorption by immersion and capillarity, carbonation and chloride penetration were assessed to evaluate the durability performance of hardened concrete, as well as shrinkage. The results obtained in the various tests show that, with the increase of recycling cycles, the recycled coarse aggregates demonstrate a quality decrease in their properties, resulting in a worse durability and shrinkage performance of the resulting concrete. Furthermore, it is shown that the decrease in performance tends to slow down with the increase of the recycling cycles, thus presenting an asymptotic behaviour. However, in most cases, it was not possible to establish that three recycling cycles were enough to stabilize the properties.