Browsing by Author "Coutinho, J. T."
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- Assessment of aerosol emission sources in a traffic site combining on-line and off-line measurementsPublication . Coutinho, J. T.; Canha, Nuno; Galinha, C.; Martins, V.; Faria, Tiago; Almeida-Silva, Marina; Lage, J.; Rigler, M.; Mocnik, G.; Diapouli, E.; Eleftheriadis, K.; Almeida, Susana MartaIn urban areas, evidence from epidemiological and experimental studies show that traffic-related air pollution has adverse effects on respiratory and cardiovascular systems. Urban air pollution accounts for 3% of mortality from cardiopulmonary disease and 1% of mortality from acute respiratory infections in children under 5 years, worldwide. Therefore, disease and mortality associated with vehicle emissions represent a substantial challenge in public health. Source apportionment, using receptor models, is an essential tool to support the implementation of the European and Member States legislation on air quality and principally to reduce the impact of exposure to Air Particulate Matter (PM) on human health. This work was developed in the framework of the Interreg Med REMEDIO project and aims to assess the aerosol emission sources in an urban traffic site, located in the outskirts of Lisbon.
- Assessment of particulate matter levels and sources in a street canyon at Loures, Portugal: a case study of the REMEDIO projectPublication . Almeida-Silva, Marina; Canha, Nuno; Vogado, Filipa; Baptista, P. C.; Faria, A. V.; Faria, T.; Coutinho, J. T.; Alves, C.; Almeida, S. M.Air quality in urban environments is directly related to structural aspects of streets and traffic variables, justifying the need for local assessments. This information is crucial to obtain accurate and reliable statistical modeling of the implementation of different mitigation scenarios aiming to improve the local air quality management. The present study intended to assess temporal trends of particulate matter levels in a street canyon of the urban area of Moscavide (Loures, Portugal) for one-month in autumn of 2016. Moreover, fine and coarse particles were characterized by their carbonaceous and elemental contents in order to identify the main pollution sources affecting the study area. Particle concentration peaks were observed during the daytime and were associated with traffic intensity due to commuting. During the studied period, no exceedances of the limit values set by the European legislation were registered. The natural sources sea salt and mineral dust contributed, on average, to 6 and 8% of PM10 levels. The Fe/Cu ratios indicated the contribution of wear emissions from road traffic. Enrichment of anthropogenic elements in PM was found. Several traffic markers were identified from specific correlations between elements (good: Cu–Mn, Cu–Pb; moderate: Cu–Zn, Mn–Zn, Pb–Zn), highlighting the contribution of local traffic to PM levels. This information is valuable to understand the possible health effects of particulate matter levels on citizens due to their exposure and to establish a reference scenario with which the future implementation of mitigation measures targeting local traffic can be compared to assess improvements in air quality in the studied street canyon.
- Growth of (Perylene)(2) [PD(MNT)(2)] crystalsPublication . Afonso, M. L.; Silva, R. A. L.; Matos, Manuel; Lopes, E. B.; Coutinho, J. T.; Pereira, L. C. J.; Henriques, R. T.; Almeida, M.The conditions for [pd(mnt)(2)]he growth of [pd(mnt)(2)]Perylene) [pd(mnt)(2)] [Pd(mnt) [pd(mnt)(2)]] crystals either by chemical oxidation and electrochemical routes are [pd(mnt)(2)]escribed. The electrocrystallisation is limited by close [pd(mnt)(2)]roximity of [pd(mnt)(2)]he oxidation [pd(mnt)(2)]otentials of [pd(mnt)(2)]he [pd(mnt)(2)]erylene [pd(mnt)(2)]onor and [Pd(mnt) [pd(mnt)(2)]] - anion, and [pd(mnt)(2)]epending on [pd(mnt)(2)]he experimental conditions [pd(mnt)(2)]ifferent [pd(mnt)(2)]orphologies can be obtained. [pd(mnt)(2)]Per) [pd(mnt)(2)] [Pd(mnt) [pd(mnt)(2)]] crystals obtained by elecrocrystallisation were found [pd(mnt)(2)]o be [pd(mnt)(2)]ainly of [pd(mnt)(2)]he β-polymorph with [pd(mnt)(2)]roperties comparable [pd(mnt)(2)]o [pd(mnt)(2)]he Cu, Ni and Pt analogues [pd(mnt)(2)]reviously [pd(mnt)(2)]escribed at variance with [pd(mnt)(2)]hose obtained by chemical oxidation which are [pd(mnt)(2)]ainly of [pd(mnt)(2)]he α-polymorph.