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Advisor(s)
Abstract(s)
The conditions for [pd(mnt)(2)]he growth of [pd(mnt)(2)]Perylene) [pd(mnt)(2)] [Pd(mnt) [pd(mnt)(2)]] crystals either by chemical oxidation and electrochemical routes are [pd(mnt)(2)]escribed. The electrocrystallisation is limited by close [pd(mnt)(2)]roximity of [pd(mnt)(2)]he oxidation [pd(mnt)(2)]otentials of [pd(mnt)(2)]he [pd(mnt)(2)]erylene [pd(mnt)(2)]onor and [Pd(mnt) [pd(mnt)(2)]] - anion, and [pd(mnt)(2)]epending on [pd(mnt)(2)]he experimental conditions [pd(mnt)(2)]ifferent [pd(mnt)(2)]orphologies can be obtained. [pd(mnt)(2)]Per) [pd(mnt)(2)] [Pd(mnt) [pd(mnt)(2)]] crystals obtained by elecrocrystallisation were found [pd(mnt)(2)]o be [pd(mnt)(2)]ainly of [pd(mnt)(2)]he β-polymorph with [pd(mnt)(2)]roperties comparable [pd(mnt)(2)]o [pd(mnt)(2)]he Cu, Ni and Pt analogues [pd(mnt)(2)]reviously [pd(mnt)(2)]escribed at variance with [pd(mnt)(2)]hose obtained by chemical oxidation which are [pd(mnt)(2)]ainly of [pd(mnt)(2)]he α-polymorph.
Description
Keywords
Electrochemical Growth Aromatic Compounds Perylene Salts Palladium Dithiolates Molecular Conductors Density-Wave Dynamics Dimensional Molecular Conductors Metals (PER)2M(MNT)2 Magnetic-Properties Complexes Perylene MNT=Maleonitridithiolate Transport Family FE
Citation
AFONSO, M. L.; [et al] – Growth of (Perylene)(2) [PD(MNT)(2)] crystals. Journal of Crystal Growth. ISSN: 00220248. Vol. 340, nr. 1 (2012), pp. 56-60
Publisher
Elsevier