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Advisor(s)
Abstract(s)
Abstract—A new efficient method for deprotection of TBDMS derivatives of phenols, primary alcohols, carboxylic acids and secondary amines, consisting of SbCl5 and MeCN with 0.1% water (w/v), is reported. It effects inter alia desilylation of a
CH2OTBDMS group in the presence of a ketal function.
Description
Keywords
Química TBDMS
Citation
Glória PM, Prabhakar S, Lobo AM, Gomes M. SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation. Tetrahedron Lett. 2003;44:8819-21.