| Name: | Description: | Size: | Format: | |
|---|---|---|---|---|
| 2.74 MB | Adobe PDF |
Authors
Barata, Patrícia
Prata, José Virgílio
Advisor(s)
Abstract(s)
Two highly fluorescent calix[4]arene-containing phenylene-alt-ethynylene-carbazolylene polymers (Calix-PPE-CBZs) were used in the detection of explosives from the nitroaromatic compounds (NACs) family, in solution and in vapour phases. Both fluorophores exhibit high sensitivity and selectivity towards NACs detection. The quenching efficiencies in solution, assessed through static Stern-Volmer constants (K-SV), follow the order picric acid (PA) >> 2,4,6-trinitrotoluene (TNT) > 2,4-dinitrotoluene > (2,4-DNT) > nitrobenzene (NB). These correlate very well with the NACs electron affinities, as evaluated from their lowest unoccupied molecular orbitals (LUMOs) energies, indicating a photo-induced electron transfer as the dominant mechanism in fluorescence quenching. Moreover, and most interesting, detection of TNT, 2,4-DNT and NB vapours via thin-films of Calix-PPE-CBZs revealed a remarkably sensitive response to these analytes, comparable to state-of-the-art chemosensors. The study also analyses and compares the current results to previous disclosed data on the detection of NACs by several calix[4]arene-based conjugated polymers and non-polymeric calix[4]arenes-carbazole conjugates, overall highlighting the superior role of calixarene and carbazole structural motifs in NACs' detection performance. Density functional theory (DFT) calculations performed on polymer models were used to support some of the experimental findings.
Description
Keywords
Calix[4]arene Conjugated polymer Carbazole Fluorescence Sensor Explosives
Citation
BARATA, Patrícia D.; PRATA, José V. – Fluorescent calix[4]arene-carbazole-containing polymers as sensors for nitroaromatic explosives. Chemosensors. ISSN 2227-9040. Vol. 8, N.º 4 (2020), pp. 1-15
Publisher
MDPI