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Advisor(s)
Abstract(s)
The first lanthanopolyoxometalate-supported bifunctional periodic mesoporous organosilica (BPMO) composite is here reported. The incorporation of decatunsgstoeuropate anions ([Eu(W5O18)(2)](9-)) within the porous channels of an ethylene-bridged TIVIAPS-functionalized BPMO produced a luminescent material exhibiting a strong red emission under UV irradiation. Photoluminescence studies showed an efficient energy transfer process to the lanthanide emitting center in the material (antenna effect). A significant change in the coordination environment of Eu3+ ions was observed after its incorporation into the TMAPS-functionalized material. The possible reason for this is discussed within the paper.
Description
Keywords
Polyoxometalate Mesoporous silica Composite Luminescence Lanthanide
Citation
Granadeiro, Carlos M. [et al] - A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica. Microporous and Mesoporous Materials. ISSN: 1387-1811. Vol. 234,(novembro2016), pp. 248-256
