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- Nanoparticle exposure and hazard in the ceramic industry: an overview of potential sources, toxicity and health effectsPublication . Bessa, M.J.; Brandão, Fátima; Viana, Mar; Gomes, João; Monfort, Eliseo; Cassee, Flemming R.; Fraga, Sónia; Teixeira, JoaoThe ceramic industry is an industrial sector of great impact in the global economy that has been benefiting from advances in materials and processing technologies. Ceramic manufacturing has a strong potential for airborne particle formation and emission, namely of ultrafine particles (UFP) and nanoparticles (NP), meaning that workers of those industries are at risk of potential exposure to these particles. At present, little is known on the impact of engineered nanoparticles (ENP) on the environment and human health and no established Occupational Exposure Limits (OEL) or specific regulations to airborne nanoparticles (ANP) exposure exist raising concerns about the possible consequences of such exposure. In this paper, we provide an overview of the current knowledge on occupational exposure to NP in the ceramic industry and their impact on human health. Possible sources and exposure scenarios, a summary of the existing methods for evaluation and monitoring of ANP in the workplace environment and proposed Nano Reference Values (NRV) for different classes of NP are presented. Case studies on occupational exposure to ANP generated at different stages of the ceramic manufacturing process are described. Finally, the toxicological potential of intentional and unintentional ANP that have been identified in the ceramic industry workplace environment is discussed based on the existing evidence from in vitro and in vivo inhalation toxicity studies.
- Characterization of airborne emission of nanoparticles in the ceramic industry in PortugalPublication . Esteves, H.; Bordado, J.; Gomes, João; Miranda, R.; Albuquerque, PaulaThe objective of this study was to evaluate occupational exposure to nanoparticles during some tasks performed in different production processes of different ceramic industries in Portugal, to select the places of greatest occupational exposure through the analysis of the sampled data, to verify what is the pulmonary accumulation in these places, to identify the composition of the released nanoparticles, apply a Control Banding Tool and try to understand which companies require more risk control measures. The study was carried out in three different national ceramics production industries, one for sanitary ceramics production, another for porcelain crockery production, and finally another for the production of ornamental crockery (red paste). It is concluded that occupational exposure values to nanoparticles are high in all cases and that nanoparticles are very small in size (11.5 to 15.4 nm). Existing risk control measures are insufficient and verified risk levels are high (Risk Level 3 and 4). The chemical composition of the analyzed nanoparticles is similar regardless of the typology of the ceramic production plant and their chemical composition as a percentage of certain materials has a direct influence on crystallinity.
- Risk assessment of welding operations and processes in terms of ultrafine particles emissionsPublication . Gomes, João; Miranda, Rosa M.; Esteves, Helder M.; Albuquerque, PaulaWelding is extensively used in metallic construction worldwide, in spite of being able to produce dangerous fumes that may be hazardous to the welder’s health. It is estimated that, presently, 1-2% of workers from different professional backgrounds (which accounts for more than 3 million persons) are subject to welding fume and gas action. Recently, studies have proved the existence of ultrafine particle emissions, from welding processes, thus increasing the health risks to exposed welders. In particular, it was found that the amount of emitted particles (measured by particle number and alveolar deposited surface area) is clearly dependent on the distance to the welding front, and also on the main welding parameters, namely the applied current intensity, heat input, nature of base metal, nature of addition metal, and nature of welding gases used. The emission of airborne ultrafine particles increases with the increase of current intensity as the fume-formation rate does. In regards to welding gas mixtures, higher emissions are observed for more oxidant mixtures, that is, mixtures with a higher CO2 content, which result in higher electric arc stability. These mixtures originate higher concentrations of ultrafine particles (as measured by the number of particles per cm3 of air) and higher values of the alveolar deposited surface area of particles, thus resulting in more severe worker exposure. Combining the obtained data, it is possible to compare different welding processes and operating conditions, in order to assess different levels of welder’s exposure. Also, the graphical representation of measured concentrations of airborne ultrafine particles, with time and distance, allows us to define “safe” and “critical” regions within a welding workshop in terms of welder exposure. This information may be combined with the results of risk analysis derived by control banding and helps to categorize the sites where regulatory measures such as operation containment or dedicated exhaust ventilation need to be implemented.