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- Thermal performance of concrete with reactive magnesium oxide as an alternative binderPublication . Forero Valencia, Javier Andres; Bravo, Miguel; Pacheco, João; Brito, Jorge de; Evangelista, LuisThis study evaluates the thermal conductivity of concrete produced with reactive magnesium oxide (MgO) as a partial replacement for cement. MgO is a viable option for the concrete industry, mainly due to its benefits in sustainability and reducing CO2 emissions compared to cement emissions. Four different MgO's produced in Australia, Canada, and Spain were used in concrete mixes as a partial replacement of cement at 5%, 10%, and 20% by mass. The experimental results showed that the thermal conductivity is higher when MgO increases in mixes after 28 days of curing. With the incorporation of MgO, the thermal conductivity increased between 3.2% and 10.2%, and the mechanical properties declined: compressive strength between 12.7% to 26.2%, splitting tensile strength between 9.7% to 34.0%, and modulus of elasticity between -4.1% to 7.8%. Finally, it is important to highlight that the addition of different contents of MgO in the concrete mixes modified the microstructure of the cement matrix. As a result, there was an increase in porosity, which negatively influenced the mechanical properties and thermal conductivity. Therefore, the relationships between these properties were also analyzed.
- On the development of a technical specification for the use of fine recycled aggregates from construction and demolition waste in concrete productionPublication . Bravo, Miguel; Duarte, António P. C.; De Brito, Jorge; Evangelista, Luís; Pedro, DiogoThe possibility of using recycled aggregates from construction and demolition waste (CDW) in concrete is rather widely agreed upon when it comes to the use of coarse recycled aggregates. However, this is not the case when fine recycled aggregates (FRA) are considered, as it is deemed that these seriously impair the behaviour of concrete. Hence, this work presents a technical specification proposal for the use of FRA from CDW in concrete, to attempt to fill this gap in legislation. The specification is based on a wide collection of experimental results, from which it is shown that for low incorporation ratios (up to 25%), the properties of concrete with FRA from CDW are comparable to those of a reference concrete. The intended international scope of the specification is ensured by the fact that FRA from CDW are typified by composition (percentage of concrete, masonry, glass, etc.) rather than by geographical origin or construction type. It is shown that, after typifying the FRA and assuming, as per design, the acceptable percentage losses (relative to a reference concrete) of mechanical, durability-related and long-term physical properties, if the maximum incorporation ratios proposed of each type of FRA are used, the variation of properties remains within the limits established.
- Magnesia (MgO) production and characterization, and its influence on the performance of cementitious materials: a reviewPublication . Nobre, José; Hawreen, Ahmed; Bravo, Miguel; Evangelista, Luis; De Brito, JorgeThis paper presents a literature review concerning the characteristics of MgO (magnesium oxide or magnesia) and its application in cementitious materials. It starts with the characterization of MgO in terms of production processes, calcination temperatures, reactivity, and physical properties. Relationships between different MgO characteristics are established. Then, the influence of MgO incorporation on the properties of cementitious materials is investigated. The mechanical strength and durability behaviour of cement pastes, mortars and concrete mixes made with MgO are discussed. The studied properties of MgO-cement mixes include compressive strength, flexural strength, tensile strength, modulus of elasticity, water absorption, porosity, carbonation, chloride ion penetration, shrinkage, expansion, and hydration degree. In addition, microscopic analyses of MgO-cement mixes are also assessed. Summarizing the results of different studies, it is concluded that MgO incorporation in cementitious materials generally decreases the mechanical strength and shrinkage, and increases the porosity, expansion, carbonation and chloride ion migration. However, it should be emphasized that the properties of the specific MgO used (mainly the calcination temperature, the reactivity and the surface area) have a significant influence on the characteristics of the cementitious materials produced.
- Durability and shrinkage of concrete with CDW as recycled aggregates: Benefits from superplasticizer’s incorporation and influence of CDW compositionPublication . Bravo, Miguel; De Brito, Jorge; Evangelista, Luis; Pacheco, JoãoThe shrinkage and durability properties of a total of 34 concrete mixes with recycled aggregates produced from different untreated construction and demolition waste (CDW) were tested. The effect of a polycarboxylic superplasticizer on the enhancement of these properties is presented, discussed, and compared with the findings of studies on concrete whose recycled aggregates are sourced from concrete. All properties were significantly affected by recycled aggregate incorporation and this effect was strongly dependent on the properties of the recycled aggregates of each specific source. The superplasticizer was less efficient in mixes with CDW than when the recycled aggregates were produced from concrete, the most common source of recycled aggregates in experimental works, despite untreated CDW being more practical and desirable from an industrial and environmental perspective.
- Performance of mortars with commercially-available reactive magnesium oxide as alternative binderPublication . Bravo, Miguel; Forero, Javier A.; Nobre, José; De Brito, Jorge; Evangelista, LuisThis paper intends to analyze the performance of mortars with reactive MgO, as a sustainable alternative to cement. Six different MgOs from Australia, Canada, and Spain were used in the production of mortars as partial substitutes for cement, namely 5%, 10%, 15%, 20%, and 25% (by weight). MgOs with different levels of reactivity were used to analyze its influence on the performance of MgO mortars. In order to evaluate the mechanical performance of these mortars, compressive strength, flexural strength, dynamic modulus of elasticity, and ultrasonic pulse velocity tests were performed. Compressive strength tests showed that the use of 25% reactive MgO can cause a decrease of this property of between 28% and 49%. The use of reactive MgO affected the other mechanical properties less. This paper also intends to analyze the durability performance of mortars with reactive MgO. To that effect, water absorption by capillarity was assessed. In this research, the effect of using MgO on the shrinkage was also analyzed. It was found that shrinkage may decrease by more than a half in some cases.