Browsing by Author "Nunes, T."
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- Impact of Sahara dust transport on Cape Verde atmospheric element particlesPublication . Almeida-Silva, Marina; Almeida, Susana Marta; Freitas, M. C.; Pio, C. A.; Nunes, T.; Cardoso, J.The objectives of this study were to (1) conduct an elemental characterization of airborne particles sampled in Cape Verde and (2) assess the influence of Sahara desert on local suspended particles. Particulate matter (PM10) was collected in Praia city (14°94'N; 23°49'W) with a low-volume sampler in order to characterize its chemical composition by k0-INAA. The filter samples were first weighed and subsequently irradiated at the Portuguese Research Reactor. Results showed that PM10 concentrations in Cape Verde markedly exceeded the health-based air quality standards defined by the European Union (EU), World Health Organization (WHO), and U.S. Environmental Protection Agency (EPA), in part due to the influence of Sahara dust transport. The PM10 composition was characterized essentially by high concentrations of elements originating from the soil (K, Sm, Co, Fe, Sc, Rb, Cr, Ce, and Ba) and sea (Na), and low concentrations of anthropogenic elements (As, Zn, and Sb). In addition, the high concentrations of PM measured in Cape Verde suggest that health of the population may be less affected compared with other sites where PM10 concentrations are lower but more enriched with toxic elements.
- Indoor air quality in a home improvement store: gaseous pollutants, bioburden and particle-bound chemical constituentsPublication . Furst, Leonardo; Cipoli, Yago; Yubero, Eduardo; Galindo, Nuria; Viegas, Carla; Dias, Marta; Nunes, T.; Igrejas, Getúlio; Feliciano, Manuel; Alves, CéliaEnsuring good air quality is essential for safeguarding human health, requiring monitoring to comprehend air composition and formulate effective interventions. This study focused on indoor and outdoor air quality monitoring within a home improvement and gardening franchise store in northeastern Portugal. Real-time optical monitors recorded levels of particulate matter below 10 µm (PM10), while PM10 gravimetric sampling was performed to analyse carbonaceous constituents and metal(loid)s. Continuous monitoring also included CO2 and comfort parameters. Volatile organic compounds (VOCs), bacteria, and fungi were passively sampled. During labour hours, indoor PM10 concentrations exceeded the national protection threshold, reaching 45.4 ± 15.2 μg/m3, compared to 27.1 ± 9.96 μg/m3 outdoors. The presence of elements from tyre and brake wear and road dust resuspension suggested that outdoor particles were mainly from non-exhaust traffic emissions. Indoors, the abundance of soil-related elements points to the resuspension of mineral dust as an important source of PM10. Also, anthropogenic constituents associated with activities (e.g., wood sawing) and products sold in the store contributed to indoor particle levels. Dominant indoor VOCs were α-pinene, limonene, and hexanal. The most abundant elements in PM10 indoors were Ca, Fe and Zn, with values of 658 ± 297, 273 ± 141, 172 ± 67.4 ng/m3, respectively. Common fungi included Trichoderma sp. and Penicillium sp., while colony-forming bacterial units were most prevalent in the gardening and heating sections. This comprehensive study highlights the need to implement indoor air quality monitoring strategies in commercial spaces, particularly with regard to particulate matter and associated pollutants.