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Advisor(s)
Abstract(s)
For the first time, a magnetic C-scorpionate catalyst was prepared from the iron(II) complex [FeCl2{_3-HC(pz)3}] (pz = pyrazol-1-yl) and ferrite, using the sustainable mechanochemical synthetic procedure. Its catalytic activity for the cyclohexane oxidation with tert-butyl hydroperoxide (TBHP) was evaluated in different conditions, namely under microwave irradiation and under the effect of an external magnetic field. The use of such magnetic conditions significantly shifted the catalyst alcohol/ketone selectivity, thus revealing a promising, easy new protocol for tuning selectivity in important catalytic processes.
Description
Keywords
Magnetic C-scorpionate Catalyst Oxidation Selectivity Mechanochemical Cyclohexane Iron
Citation
RIBEIRO, Ana P. C.; [et al] – New trendy magnetic C-scorpionate iron catalyst and its performance towards cyclohexane oxidation. Catalysts. ISSN 2073-4344. Vol. 8, N.º 2 (2018), pp. 1-11
Publisher
MDPI