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Aryleneethynylene trimers bearing calix[4]arenes: synthesis, optical properties and self-assembling studies

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New homoditopic bis-calix[4]arene-carbazole conjugates, armed with hydrophilic carboxylic acid functions at their lower rims, are disclosed. Evidence for their self-association in solution was gathered from solvatochromic and thermochromic studies, as well as from gel-permeation chromatography analysis. Their ability to function as highly sensitive sensors toward polar electron-deficient aromatic compounds is demonstrated.

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Calix[4]arenes Fluorescence sensors Self-assembling Supramolecular polymers

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PRATA, José V.; BARATA, Patrícia D. - Aryleneethynylene trimers bearing calix[4]arenes: synthesis, optical properties and self-assembling studies. Macromolecular Symposia. ISSN.1022-1360. Vol. 352, N.º 1, SI(2015), pp. 87-94

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Wiley-V C H Verlag GMBH

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