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Nickel (ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for heck and henry reactions

dc.contributor.authorDa Costa Ribeiro, Ana Paula
dc.contributor.authorKarabach, Yauhen Yu
dc.contributor.authorMartins, Luisa
dc.contributor.authorMahmoud, Abdallah G.
dc.contributor.authorGuedes Da Silva, M. Fátima C.
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2017-07-13T10:15:13Z
dc.date.available2017-07-13T10:15:13Z
dc.date.issued2016
dc.description.abstractNickel (II)-triazapentadienate complexes, [Ni(tap)(2)], are synthesized and found to act as catalysts in the Heck reaction of deactivated aryl halides. The use of room-temperature ionic liquids instead of organic solvents allows easy separation of the catalyst from the products and substrates. The synthesized complexes also catalyse the Henry reaction of benzaldehydes with nitroethane, at 25 degrees C, leading to the corresponding nitroalkanols with diastereoselectivity in favour of the anti isomer.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationRIBEIRO, Ana P. C. [et al]. - Nickel (ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for heck and henry reactions. RSC Advances. ISSN 2046-2069. Vol. 6, N.º 35 (2016), pp. 29159-29163pt_PT
dc.identifier.doi10.1039/c6ra02989bpt_PT
dc.identifier.issn2046-2069
dc.identifier.urihttp://hdl.handle.net/10400.21/7269
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.relation.publisherversion: http://www.rsc.org/suppdata/c6/ra/c6ra02989b/c6ra02989b1.pdfpt_PT
dc.titleNickel (ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for heck and henry reactionspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage29163pt_PT
oaire.citation.issue35
oaire.citation.startPage29159pt_PT
oaire.citation.titleRSC Advancespt_PT
oaire.citation.volume6pt_PT
person.familyNameda Costa Ribeiro
person.familyNameMartins
person.familyNameMahmoud
person.familyNameGuedes da Silva
person.familyNamePombeiro
person.givenNameAna Paula
person.givenNameLuisa
person.givenNameAbdallah G.
person.givenNameM. Fátima C.
person.givenNameArmando
person.identifier1336277
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person.identifier.orcid0000-0001-8323-888X
person.identifier.ridF-8341-2014
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person.identifier.ridQ-3032-2016
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person.identifier.scopus-author-id22235818800
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id56176710300
person.identifier.scopus-author-id6701761571
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
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