Repository logo
 
Publication

Catalytic performance of Fe(II)-scorpionate complexes towards cyclohexane oxidation in organic, ionic liquid and/or supercritical CO2 media: a comparative study

2017-08Journal article Restricted access
Simple item page
dc.contributor.authorDa Costa Ribeiro, Ana Paula
dc.contributor.authorMartins, Luisa
dc.contributor.authorAlegria, Elisabete
dc.contributor.authorMatias, Inês A. S.
dc.contributor.authorDuarte, Tiago A. G.
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2017-09-19T14:35:35Z
dc.date.available2017-09-19T14:35:35Z
dc.date.issued2017-08
dc.description.abstractThe catalytic activity of the iron(II) C-scorpionate complexes [FeCl2{HC(pz)3}] 1 (pz = pyrazol-1-yl) and [FeCl2{HOCH2C(pz)3}] 2, and of their precursor FeCl2·2H2O 3, towards cyclohexane oxidation with tert-butyl hydroperoxide was evaluated and compared in different media: acetonitrile, ionic liquids (1-butyl-3-methylimidazolium hexafluorophosphate, [bmim][PF6], and 1-butyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate, [bmim][FAP]), supercritical carbon dioxide (scCO2), and scCO2/[bmim][X] (X = PF6 or FAP) mixtures. The use of such alternative solvents led to efficient and selective protocols for the oxidation of cyclohexane. Moreover, tuning the alcohol/ketone selectivity was possible by choosing the suitable solvent.pt_PT
dc.description.sponsorshipUID/QUI/00100/2013
dc.description.sponsorshipPTDC/QEQ-QIN/3967/2014
dc.description.sponsorshipPTDC/QEQ-ERQ/1648/2014
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationRIBEIRO, Ana P. C. [et al] - Catalytic performance of Fe(II)-scorpionate complexes towards cyclohexane oxidation in organic, ionic liquid and/or supercritical CO2 media: a comparative study. Catalysts. ISSN 2073-4344. Vol. 7, N.º 8 (2017), Article Number 230pt_PT
dc.identifier.doi10.3390/catal7080230pt_PT
dc.identifier.issn2073-4344
dc.identifier.urihttp://hdl.handle.net/10400.21/7375
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherMDPIpt_PT
dc.relation.publisherversionhttp://www.mdpi.com/2073-4344/7/8/230/pdfpt_PT
dc.subjectIonic liquidpt_PT
dc.subjectSupercritical carbon dioxidept_PT
dc.subjectCyclohexanept_PT
dc.subjectOxidationpt_PT
dc.subjectC-scorpionatept_PT
dc.subjectCatalystpt_PT
dc.titleCatalytic performance of Fe(II)-scorpionate complexes towards cyclohexane oxidation in organic, ionic liquid and/or supercritical CO2 media: a comparative studypt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.issue8pt_PT
oaire.citation.titleCatalystspt_PT
oaire.citation.volume7pt_PT
person.familyNameda Costa Ribeiro
person.familyNameMartins
person.familyNameAlegria
person.familyNamePombeiro
person.givenNameAna Paula
person.givenNameLuisa
person.givenNameElisabete
person.givenNameArmando
person.identifier1336277
person.identifier637885
person.identifier863202
person.identifier.ciencia-idE115-5C31-30F4
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.ciencia-id8C1F-851A-9F1C
person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0003-4323-4328
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0003-4060-1057
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridF-8341-2014
person.identifier.ridG-6210-2011
person.identifier.ridE-9945-2012
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id22235818800
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id8315848300
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationebe0b25e-d8b0-4c6a-ab27-91f199d36347
relation.isAuthorOfPublication8ed70b09-b4d3-4a5d-9f75-12b13a332204
relation.isAuthorOfPublication6d781c38-c45e-4159-b795-8c8675606160
relation.isAuthorOfPublication6d18ff2e-5c33-4010-b1e7-964c72349813
relation.isAuthorOfPublication.latestForDiscovery8ed70b09-b4d3-4a5d-9f75-12b13a332204

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
Catalytic_LMDRSMartins_ADEQ.pdf
Size:
1.11 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

ISEL - Eng. Quim. Biol. - Artigos