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Eco-friendly synthesis of indo dyes mediated by a bacterial laccase

dc.contributor.authorSousa, Ana Catarina
dc.contributor.authorPiedade, M. Fatima M.
dc.contributor.authorMartins, Ligia O.
dc.contributor.authorRobalo, Maria Paula
dc.date.accessioned2017-07-12T09:24:51Z
dc.date.available2017-07-12T09:24:51Z
dc.date.issued2016
dc.description.abstractSeveral aminoindamine and indoaniline dyes were obtained in good to excellent yields (64-98%) by oxidative cross-coupling between 1,4-phenylenediamine (1), 4-aminophenol (2) or 2,5-diaminotoluene (3) and several meta- and meta, para-substituted couplers (4a-j) using a green biocatalyst, the bacterial enzyme CotA-laccase from Bacillus subtilis, in water and under mild conditions of pH and temperature. Our results show that the enzymatic route described represents an efficient and sustainable alternative to the chemical synthesis of indo dyes, with a potentially high impact in the cosmetic and hair dye industries.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationSOUSA, Ana Catarina [et al] - Eco-friendly synthesis of indo dyes mediated by a bacterial laccase. Green Chemistry. ISSN: 1463-9262. Vol. 18, N.º 22 (2016), pp. 6063-6070pt_PT
dc.identifier.doi10.1039/c6gc02050jpt_PT
dc.identifier.issn1463-9262
dc.identifier.urihttp://hdl.handle.net/10400.21/7265
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.relation.publisherversionhttp://www.rsc.org/suppdata/c6/gc/c6gc02050j/c6gc02050j2.pdfpt_PT
dc.titleEco-friendly synthesis of indo dyes mediated by a bacterial laccasept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage6070pt_PT
oaire.citation.issue22pt_PT
oaire.citation.startPage6063pt_PT
oaire.citation.titleGREEN CHEMISTRYpt_PT
oaire.citation.volume18pt_PT
person.familyNameSousa
person.familyNameRobalo
person.givenNameAna Catarina
person.givenNameMaria Paula
person.identifier.ciencia-idE81E-0596-BF29
person.identifier.ciencia-idE11C-A704-9C18
person.identifier.orcid0000-0001-6133-7406
person.identifier.orcid0000-0002-8200-6910
person.identifier.ridU-3597-2017
person.identifier.ridB-2002-2012
person.identifier.scopus-author-id9269662100
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication2ec1bb85-33cd-4e24-b84f-0c965d84d25b
relation.isAuthorOfPublication823a9498-17ab-451f-bb8f-56338643ac0c
relation.isAuthorOfPublication.latestForDiscovery2ec1bb85-33cd-4e24-b84f-0c965d84d25b

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