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Orientador(es)
Resumo(s)
Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions.
Descrição
Palavras-chave
Schiff-base complex Manganese(III) Salen complexes Ray-Absorption spectroscopy Wall carbon nanotubes Peroxidative oxidation Activated carbon Hydrogen-Peroxide Coordination-compounds Gold(III) complexes Rhenium complexes
Contexto Educativo
Citação
ALMEIDA, M. Peixoto de; MARTINS, L. M. D. R. S.; CARABINEIRO, S. A. C. ; LAUTERBACH, T. ; ROMINGER, F.; HASHMI, A. S. K.; POMBEIRO, A. J. L.; FIGUEIREDO, J. L. - Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation. Catalysis Science & Technology. ISSN 2044-4753. Vol. 3, nr. 11 (2013), p. 3056-3069.