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Advisor(s)
Abstract(s)
The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.
Description
Keywords
Cyclohexane oxidation Hydrogen-peroxide Aerobic oxidation Complexes XPS Radicals FE
Citation
MARTINS, Luisa Margarida Dias Ribeiro de Sousa; [et al.] - Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation. Dalton Transactions. ISSN 1477-9226. Vol. 45, N.º 16, (2016), pp. 6816-6819
Publisher
Royal Soc Chemistry