Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation

Martins, Luisa; Ribeiro, A. P. C.; Carabineiro, S. A. C.; Figueiredo, J. L.; Pombeiro, Armando

http://hdl.handle.net/10400.21/6276

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Autores

Martins, Luisa

Ribeiro, A. P. C.

Carabineiro, S. A. C.

Figueiredo, J. L.

Pombeiro, Armando

Resumo(s)

The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.

Palavras-chave

Cyclohexane oxidation Hydrogen-peroxide Aerobic oxidation Complexes XPS Radicals FE

URI

http://hdl.handle.net/10400.21/6276

Citação

MARTINS, Luisa Margarida Dias Ribeiro de Sousa; [et al.] - Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation. Dalton Transactions. ISSN 1477-9226. Vol. 45, N.º 16, (2016), pp. 6816-6819