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Nanofiltration of surface water for the removal of endocrine disruptors

dc.contributor.authorSalvaterra, Ana Filipa
dc.contributor.authorSarmento, Georgina
dc.contributor.authorMinhalma, Miguel
dc.contributor.authorde Pinho, Maria Norberta
dc.date.accessioned2013-02-15T18:23:25Z
dc.date.available2013-02-15T18:23:25Z
dc.date.issued2011-11
dc.description.abstractThe assessment of surface water nanofiltration (NF) for the removal of endocrine disruptors (EDs) Nonylphenol Ethoxylate (IGEPAL), 4-Nonylphenol (NP) and 4-Octylphenol (OP) was carried out with three commercial NF membranes - NF90, NF200, NF270. The permeation experiments were conducted in laboratory flat-cell units of 13.2 x 10(-4) m(2) of surface area and in a DSS Lab-unit M20 with a membrane surface area of 0.036 m2. The membranes hydraulic permeabilities ranged from 3.7 to 15.6 kg/h/m(2)/bar and the rejection coefficients to NaCl, Na2SO4 and Glucose are for NF90: 97%, 99% and 97%, respectively; for NF200: 66%, 98% and 90%, respectively and for NF270: 48%, 94% and 84%, respectively. Three sets of nanofiltration experiments were carried out: i) NF of aqueous model solutions of NP, IGEPAL and OP running in total recirculation mode; ii) NF of surface water from Rio Sado (Settibal, Portugal) running in concentration mode; iii) NF of surface water from Rio Sado inoculated with NP, IGEPAL and OP running in concentration mode. The results of model solutions experiments showed that the EDs rejection coefficients are approximately 100% for all the membranes. The results obtained for the surface water showed that the rejection coefficients to natural organic Matter (NOM) are 94%, 82% and 78% for NF90, NF200 and NF 270 membranes respectively, with and without inoculation of EDs. The rejection coefficients to EDs in surface water with and without inoculation of EDs are 100%, showing that there is a fraction of NOM of high molecular weight that retains the EDs in the concentrate and that there is a fraction of NOM of low molecular weight that permeates through the NF membranes free of EDs.por
dc.identifier.citationSALVATERRA, Ana Filipa; SARMENTO, Georgina; MINHALMA, Miguel; de PINHO, Maria Norberta - Nanofiltration of surface water for the removal of endocrine disruptors. Desalination and Water Treatment. ISSN 1944-3994. Vol. 35, n.º 1-3 (2011) p. 54-61.por
dc.identifier.issn1944-3994
dc.identifier.urihttp://hdl.handle.net/10400.21/2220
dc.language.isoengpor
dc.publisherDesalination Publpor
dc.subjectNanofiltrationpor
dc.subjectSurface Water Treatmentpor
dc.subjectEndocrine Disruptorspor
dc.subjectNatural Organic Matterpor
dc.subjectDrinking Waterpor
dc.subjectNonylphenol Ethoxylatepor
dc.subject4-Nonylphenolpor
dc.subject4-Octylphenolpor
dc.subjectNatural Organic-Matterpor
dc.subjectAlkylphenol Polyethoxylate Surfactantspor
dc.subjectSolid-Phase Extractionpor
dc.subjectRejection Propertiespor
dc.subjectAquatic Environmentpor
dc.subjectBisphenol-Apor
dc.subjectMembranespor
dc.subjectUltrafiltrationpor
dc.subjectNonylphenolpor
dc.subjectDrinkingpor
dc.titleNanofiltration of surface water for the removal of endocrine disruptorspor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceHopkintonpor
oaire.citation.endPage61por
oaire.citation.issue1-3por
oaire.citation.startPage54por
oaire.citation.titleDesalination and Water Treatmentpor
oaire.citation.volume35por
person.familyNameMinhalma
person.givenNameMiguel
person.identifier2161276
person.identifier.ciencia-id5C1D-13E2-201B
person.identifier.orcid0000-0002-6770-194X
person.identifier.ridC-3304-2008
person.identifier.scopus-author-id6506304514
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication8ed0648a-758d-4b1d-b364-f8ea7195308f
relation.isAuthorOfPublication.latestForDiscovery8ed0648a-758d-4b1d-b364-f8ea7195308f

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