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Electrochemical properties of Robson type macrocyclic dicopper(II) complexes

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dc.contributor.authorAlegria, Elisabete
dc.contributor.authorAnbu, Sellamuthu
dc.contributor.authorMartins, Luisa
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2018-08-01T14:04:15Z
dc.date.available2018-08-01T14:04:15Z
dc.date.issued2015
dc.description.abstractThe redox properties of the 1,10-phenanthroline containing Robson type symmetrical macrocyclic dicopper(II) complex [Cu2L(H2O.phen)2](ClO4)2 1 (L = μ-11,23-dimethyl-3,7,15,19-tetraazatricyclo-[19.3.1.18 19,13,21] he p t a c o s a-1(24) , 2, 7, 9, 11, 13(26), 14, 19, 21(25), 22-decaene-25,26-diolate) and of its dicopper(II) precursor [Cu2L(H2O)2](ClO4)2 2 have been investigated by cyclic voltammetry and controlled potential electrolysis in different organic solvents. They exhibit two consecutive reversible one-electron reductions assigned to the CuIICuII ® CuICuII ® CuICuI cathodic processes. The results suggest that, in solution, phenanthroline does not coordinate to the metal in complex 1, but its H-bonding interaction with the water ligands can be preserved.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationALEGRIA, Elisabete C. B. A.; [et al] – Electrochemical properties of Robson type macrocyclic dicopper(II) complexes. Portugaliae Electrochimica Acta. ISSN 1647-1571. Vol. 33, N.º 4 (2015), pp. 201-207pt_PT
dc.identifier.doi10.4152/pea.201504201pt_PT
dc.identifier.issn1647-1571
dc.identifier.urihttp://hdl.handle.net/10400.21/8742
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherSociedade Portuguesa de Electroquímicapt_PT
dc.relation.publisherversionhttp://www.peacta.org/articles_upload/PEA_33_4_2015_201_207.pdfpt_PT
dc.subjectRobson type macrocyclic dicopper(II) complexespt_PT
dc.subject1,10-phenanthrolinept_PT
dc.subjectcyclic voltammetrypt_PT
dc.subjectcontrolled potential electrolysispt_PT
dc.titleElectrochemical properties of Robson type macrocyclic dicopper(II) complexespt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F76451%2F2011/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FQUI%2F00100%2F2013/PT
oaire.citation.endPage207pt_PT
oaire.citation.issue4pt_PT
oaire.citation.startPage201pt_PT
oaire.citation.titlePortugaliae Electrochimica Actapt_PT
oaire.citation.volume33pt_PT
oaire.fundingStreamSFRH
oaire.fundingStream5876
person.familyNameAlegria
person.familyNameMartins
person.familyNamePombeiro
person.givenNameElisabete
person.givenNameLuisa
person.givenNameArmando
person.identifier863202
person.identifier637885
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person.identifier.orcid0000-0003-4060-1057
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridE-9945-2012
person.identifier.ridG-6210-2011
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id8315848300
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id7006067269
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
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