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Criticality of colloids with three distinct interaction patches: As simple as A, B, C?

dc.contributor.authorTavares, Jose
dc.contributor.authorTeixeira, Paulo
dc.date.accessioned2017-11-09T10:46:14Z
dc.date.available2017-11-09T10:46:14Z
dc.date.issued2017-01
dc.description.abstractWe systematically study the phase behavior of a simple model of associating fluids which consists of hard spherical particles with three short-ranged attractive sites on their surfaces (sticky spots or patches), of types A, B, and C, that can form bonds with energy ij (i,j = A,B,C). We consider realizations of the model with one, two, or three nonzero ij. Using Wertheim’s first order perturbation theory of association, we establish the minimum requirements on the bond energies for the model to exhibit a liquid-vapor critical point, and investigate the nature of criticality in each case. As a preliminary, we rigorously show that, within this theory, particles with M identical sites do not condense if M < 3, a result that was previously conjectured, but never proved.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationTAVARES, José Maria; TEIXEIRA, Paulo Ivo Cortez - Criticality of colloids with three distinct interaction patches: As simple as A, B, C?. Physical Review E. ISSN 2470-0045. Vol. 95, N.º 1 (2017), pp. 1-16pt_PT
dc.identifier.doi10.1103/PhysRevE.95.012612pt_PT
dc.identifier.issn2470-0045
dc.identifier.issn2470-0053
dc.identifier.urihttp://hdl.handle.net/10400.21/7469
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherAmerican Physical Societypt_PT
dc.subjectThermodynamic perturbation-theorypt_PT
dc.subjectColloidspt_PT
dc.subjectFluidspt_PT
dc.subjectParticlespt_PT
dc.subjectBehaviorpt_PT
dc.titleCriticality of colloids with three distinct interaction patches: As simple as A, B, C?pt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/EXCL%2FFIS-NAN%2F0083%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FFIS%2F00618%2F2013/PT
oaire.citation.endPage16
oaire.citation.issue1pt_PT
oaire.citation.startPage1
oaire.citation.titlePhysical Review Ept_PT
oaire.citation.volume95pt_PT
oaire.fundingStream3599-PPCDT
oaire.fundingStream5876
person.familyNameTavares
person.familyNameTeixeira
person.givenNameJose
person.givenNamePaulo
person.identifier.ciencia-id371D-51C6-975C
person.identifier.ciencia-idB31A-0CBD-8AC4
person.identifier.orcid0000-0002-1509-9707
person.identifier.orcid0000-0003-2315-2261
person.identifier.ridA-2891-2009
person.identifier.ridA-2682-2009
person.identifier.scopus-author-id35621140500
person.identifier.scopus-author-id7005895098
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
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relation.isAuthorOfPublication35a012c6-2e8b-402f-9b82-065843fce9aa
relation.isAuthorOfPublication.latestForDiscovery35a012c6-2e8b-402f-9b82-065843fce9aa
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