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Advisor(s)
Abstract(s)
As an extension of our previous studies concerning the free radical copolymerisation of 25,26,27-tripropoxy-28-(4-vinyl-benzyloxy)-p-tert-butylcalix[4]arene (3) with styrylic monomers, we report herein on the synthesis and characterisation of new terpolymers derived from 3, styrene and divinylbenzene, having nominal crosslinking degrees ranging from 4% to 40% wt. The terpolymers exhibited good thermal stabilities (DSC) and were prepared in good yields. Depending on the reaction conditions (dilution degree and aqueous phase to porogen ratio), materials with identical nominal crosslinking but otherwise differentiated morphologies and swelling abilities were obtained.
In a related study, the radical polymerisation of styrene was carried out in the presence of a novel calix[4]arene derivative 4, bearing two distal benzyl–vinyl groups in the lower rim. It is shown that, albeit the presence of two phenolic groups within the calixarene moiety which could have functioned as inhibitors of the free radical polymerisation, the macrocycle was able to take part in the copolymerisation reaction, yielding new soluble and crosslinked polymers. In both cases, no pendant vinyl groups were found in the polymeric materials. The probable mechanisms underlying their formation are discussed.
Description
Keywords
Calixarene Radical polymerisation Cyclopolymerisation Vinyl Styrene Linear Crosslinked
Citation
MENDES, Ana R.; [et al] – Linear and crosslinked copolymers of p-tert-butylcalix[4]arene derivatives and styrene: New synthetic approaches to polymer-bound calix[4]arenes. Reactive and Functional Polymers. ISSN 1381-5148. Vol. 65, N.º 1-2 (2005), pp. 9-21
Publisher
Elsevier