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Solvent effects on solution enthalpies of adamantyl derivatives

dc.contributor.authorMartins, Filomena
dc.contributor.authorMoreira, Luís
dc.contributor.authorNunes, Nélson
dc.contributor.authorElvas Leitao, Ruben
dc.date.accessioned2012-03-13T19:28:19Z
dc.date.available2012-03-13T19:28:19Z
dc.date.issued2010-05
dc.description.abstractSolution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving delta(cav) h (s) as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes' characteristics. New insights on the solution processes under scrutiny are presented.por
dc.identifier.citationMARTINS, F.; MOREIRA, L.; NUNES, N.; LEITÃO, Rúben Elvas - Solvent effects on solution enthalpies of adamantyl derivatives. Journal of Thermal Analysis And Calorimetry. 2010; 100 (2): pp. 483-491.por
dc.identifier.issn1388-6150
dc.identifier.urihttp://hdl.handle.net/10400.21/1295
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherSpringerpor
dc.relation.ispartofseries2;
dc.subjectBromoadamantanepor
dc.subjectAdamantanolpor
dc.subjectAdamantanonepor
dc.subjectSolution enthalpypor
dc.subjectMultiparametric equationpor
dc.subjectSolvent effectspor
dc.subjectTert-butyl chloridepor
dc.subjectThermodynamic propertiespor
dc.subjectHydroxylic solventspor
dc.subjectSolvationpor
dc.subjectAlcoholspor
dc.subjectParameterspor
dc.subjectBromidepor
dc.subjectStatepor
dc.titleSolvent effects on solution enthalpies of adamantyl derivativespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceNetherlandspor
oaire.citation.endPage491por
oaire.citation.issue100por
oaire.citation.startPage483por
oaire.citation.titleJournal of Thermal Analysis And Calorimetrypor
person.familyNameElvas Leitao
person.givenNameRuben
person.identifier.ciencia-idF41B-8A26-88D4
person.identifier.orcid0000-0002-2196-412X
person.identifier.ridD-2452-2009
person.identifier.scopus-author-id55667178200
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication440b7129-d4d9-4225-a936-ca694c0984b6
relation.isAuthorOfPublication.latestForDiscovery440b7129-d4d9-4225-a936-ca694c0984b6

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