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Advisor(s)
Abstract(s)
Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving delta(cav) h (s) as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes' characteristics. New insights on the solution processes under scrutiny are presented.
Description
Keywords
Bromoadamantane Adamantanol Adamantanone Solution enthalpy Multiparametric equation Solvent effects Tert-butyl chloride Thermodynamic properties Hydroxylic solvents Solvation Alcohols Parameters Bromide State
Citation
MARTINS, F.; MOREIRA, L.; NUNES, N.; LEITÃO, Rúben Elvas - Solvent effects on solution enthalpies of adamantyl derivatives. Journal of Thermal Analysis And Calorimetry. 2010; 100 (2): pp. 483-491.