Loading...
3 results
Search Results
Now showing 1 - 3 of 3
- Preliminary study on the use of biodiesel obtained from waste vegetable oils for blending with hydrotreated kerosene fossil fuel using Calcium Oxide (CaO) from natural waste materials as heterogeneous catalystPublication . Ozkan, Sila; Puna, Jaime; Gomes, João; Cabrita, T.; Palmeira, José; Santos, Maria TeresaIn this experimental work, calcium from natural seafood wastes was used as a heterogeneous catalyst separately or in a blend of "shell mix" for producing biodiesel. Several chemical reaction runs were conducted at varied reaction times ranging from 30 min to 8 h, at 60 degrees C, with a mass content of 5% (W-cat./W-oil) and a methanol/oil molar ratio of 12. After the purification process, the biodiesel with fatty acid methyl ester (FAME) weight content measured was higher than 99%, which indicated that it was a pure biodiesel. This work also showed that the inorganic solid waste shell mixture used as the heterogeneous catalyst can be reused three times and the reused mixture still resulted in a FAME content higher than 99%. After 40 different transesterification reactions were performed using liquid (waste cooking oils) and solid (calcium seafood shells) wastes for producing biodiesel, under the specific conditions stated above, we found a successful, innovative, and promising way to produce biodiesel. In addition, blends prepared with jet fuel A1 and biodiesel were recorded with no invalid results after certain tests, at 25 degrees C. In this case, except for the 10% blend, the added biodiesel had no significant effect on the viscosity (fluidity) of the biojet fuel.
- Calcium rich food wastes based catalysts for biodiesel productionPublication . Catarino, Maria Alice; Ramos, M.; Soares Dias, A. P.; Santos, Maria Teresa; Puna, Jaime; Gomes, JoãoBiodiesel produced from food wastes can help to solve several environmental issues: anthropogenic carbon emissions due to fossil fuels combustion and waste management. Biodiesel was produced using waste frying oils (WFO) and calcium rich food wastes such as mollusk, shrimp, eggs shells and cuttlebone to produce calcium based heterogeneous catalysts by calcination. The characterization of chalky white calcined powders by XRD showed diffraction lines typical of lime but some samples were slightly contaminated with calcite. The powders with low crystallinity showed high hydration rate presenting XRD features ascribable to nanocrystals of calcium hydroxide. The post reaction samples presented mainly lines due to calcium diglyceroxide and methoxide. Thermograms of used catalysts showed some weight loss of these calcium compounds, confirming the presence of such phases. All prepared catalysts were effective in catalyzing the methanolysis of soybean oil. A FAME yield around 96% was obtained after 2.5 h of reaction. When using WFO, the FAME yield was only 65% with simultaneous production of soap. The use of WFO and soybean oil mixtures attenuates the loss of catalytic performances. The obtained glycerin's presented a light color characteristic of heterogeneous catalyzed processes. FTIR spectra of glycerin's showed some features belonging to matter organic non glycerin and methanol. The catalyst reutilization without intermediate reactivation indicated that catalysts are somewhat stable. When WFO was used, the reused catalysts showed improved performance probably due to the formation of calcium diglyceroxide. Nevertheless, calcium diglyceroxide is bound to promote homogeneous catalysis and consequent deactivation.
- Sludge recovery from industrial wastewater treatmentPublication . Santos, Maria Teresa; Lopes, Pedro AndréIndustry is a fundamental sector that allows mass production to support a large population. As population grows, many industries produce large amounts of industrial effluents with different pollutants, that must be removed at the industrial wastewater treatment plants, with the consequent production of large amounts of sludge. The present study was conducted to identify and evaluate different sludge treatment/valorisation methodologies, being given priority to the valorisation in detriment of the elimination operations, like incineration or landfill. Therefore, sludges from the wastewater treatment plant of a resin industry, after dehydration operation by a press, were submitted to several valorisation methodologies, such as: application in anaerobic digestion aiming the production of biogas and allowing energy recovery, use in the preparation of adsorbents for the treatment of industrial wastewater, use as cement replacement in mortar production, and application of heterogeneous catalysts to produce biodiesel. The results revealed that all methodologies can be applied as sludge recovery. However, it is possible to conclude that the most promising industrial sludge treatment/recovery hypothesis is anaerobic co-digestion followed by the production of heterogeneous catalysts for biodiesel production.