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Browsing ESTeSL - Artigos by Subject "3-Aza Cope Rearrangements"
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- A dramatic effect of double bond configuration in N-oxy-3-aza Cope rearrangements: a simple synthesis of functionalised allenesPublication . Pinto, Luís; Glória, Paulo; Gomes, Mário; Rzepa, Henry S.; Prabhakar, Sundaresan; Lobo, Ana M.The first examples of low temperature N-oxy-3-aza Cope rearrangements, leading to functionalised allenes are described, where the Z-configuration of the enaminic double bond in the rearranging system proves critical.
- Studies in 3-oxy-assisted 3-aza Cope rearrangementsPublication . Gomes, Mário; Sharma, Lalit; Prabhakar, Sundaresan; Lobo, Ana M.; Glória, PauloOn thermolysis appropriately substituted N-silyloxy-N-allyl enamines undergo smooth 3,3-sigmatropic rearrangments to the corresponding N-silyloxy imino ethers.