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  • Exploring offshore sediment evidence of the 1755 CE tsunami (Faro, Portugal): implications for the study of outer shelf tsunami deposits
    Publication . Kümmerer, Vincent; Drago, Teresa; Veiga-Pires, C.; Silva, Pedro; Magalhaes, Vitor; Mena, Anxo; Lopes, Ana; Rodrigues, Ana Isabel; Schmidt, Sabine; Terrinha, Pedro; Baptista, Maria Ana
    Outer shelf sedimentary records are promising for determining the recurrence intervals of tsunamis. However, compared to onshore deposits, offshore deposits are more difficult to access, and so far, studies of outer shelf tsunami deposits are scarce. Here, an example of studying these deposits is presented to infer implications for tsunami-related signatures in similar environments and potentially contribute to pre-historic tsunami event detections. A multidisciplinary approach was performed to detect the sedimentary imprints left by the 1755 CE tsunami in two cores, located in the southern Portuguese continental shelf at water depths of 58 and 91 m. Age models based on C-14 and Pb-210(xs) allowed a probable correspondence with the 1755 CE tsunami event. A multi-proxy approach, including sand composition, grain-size, inorganic geochemistry, magnetic susceptibility, and microtextural features on quartz grain surfaces, yielded evidence for a tsunami depositional signature, although only a subtle terrestrial signal is present. A low contribution of terrestrial material to outer shelf tsunami deposits calls for methodologies that reveal sedimentary structures linked to tsunami event hydrodynamics. Finally, a change in general sedimentation after the tsunami event might have influenced the signature of the 1755 CE tsunami in the outer shelf environment.
    2020-08-19Journal article Open access Show more
  • The dark phases of the N2HDM
    Publication . Engeln, Isabell; Ferreira, Pedro Miguel; Muehlleitner, Milada Margarete; Santos, Rui; Wittbrodt, Jonas
    We discuss the dark phases of the Next-to-2-Higgs Doublet model. The model is an extension of the Standard Model with an extra doublet and an extra singlet that has four distinct CP-conserving phases, three of which provide dark matter candidates. We discuss in detail the vacuum structure of the different phases and the issue of stability at tree-level of each phase. Taking into account the most relevant experimental and theoretical constraints, we found that there are combinations of measurements at the Large Hadron Collider that could single out a specific phase. The measurement of h(125) -> gamma gamma together with the discovery of a new scalar with specific rates to tau (+)tau (-) or gamma gamma could exclude some phases and point to a specific phase.
    2020-08-19Journal article Open access Show more
  • Synthesis of Substituted 4-Arylamine-1,2-naphthoquinones in One-Pot Reactions Using CotA-Laccase as Biocatalyst
    Publication . Sousa, Ana Catarina; Santos, Iolanda; Piedade, M. Fatima M.; Martins, Lígia O.; Robalo, M. Paula
    An efficient and environmentally benign biocatalytic strategy for the synthesis of substituted 4-arylamino-1,2-naphthoquinones was developed, through a cross-coupling reaction in which the 1,2-naphthoquinone nucleus, formed in the biocatalytic process mediated by CotA-laccase from Bacillus subtilis, is the key synthetic intermediate. Electrochemical data and kinetic parameters were determined revealing a significant higher specificity of CotA-laccase for 4-amino-3-hydroxynaphthalene-1-sulfonic acid (AHNSA). This ability of CotA-laccase to discriminate between oxidisable aromatic amines allows the set-up of one-pot reactions in the presence of the enzyme, between AHNSA and a set of appropriate aromatic amines under mild reaction conditions.
    2020-08-19Journal article Open access Show more