Browsing by Author "Santos, Diogo"
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- 3D nickel foams with controlled morphologies for hydrogen evolution reaction in highly alkaline mediaPublication . Siwek, K. I.; Eugénio, S.; Santos, Diogo; Moura E Silva, Teresa; MONTEMOR, FATIMAWater electrolysis is the cleanest method for hydrogen production, and can be 100% green when renewable energy is used as electricity source. When the hydrogen evolution reaction (HER) is carried out in alkaline media, nickel (Ni) is a low cost catalyst and an interesting alternative to platinum. Still, its performance has to be enhanced to meet the high efficiency of the nobler metals, an objective that requires further tailoring of the surface area and morphology of Ni-based electrode materials. Unlike commercially available porous Ni, these features can be easily controlled via electrodeposition, a one-step process, taking advantage of the dynamic hydrogen bubble template (DHBT). Generally, changes in surface porosity and morphology have been mainly achieved by altering the main parameters, such as the current density or the deposition time. However, very scarce work has been done on the role of supporting electrolyte (i.e., its concentration and composition) in tailoring the foam features and consequently their catalytic activity. Hence, this approach paves the way to optimum design of metallic foam structures that can be obtained only with modifications in the electrolytic bath. In this work, 3D Ni foams are obtained from different composition baths by galvanostatic electrodeposition in the hydrogen evolution regime on stainless steel current collectors. Their porosity and morphology are analysed by optical microscopy and SEM. The electrochemical performance is evaluated by cyclic voltammetry, while catalytic activity towards HER and materials' stability in 8 M KOH are tested using polarisation curves and chronoamperometry measurements, respectively. The recorded high currents and extended stability of the Ni foams with dendritic morphology demonstrate its outstanding performance, making it an attractive cathode material for HER in highly alkaline media. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
- ESS design and management considering solar PV to fed off-grid EV chargerPublication . Santos, Diogo; Fonte, Pedro M; Pereira, Rita; Barata, Filipe; Almeida, Paulo; Cordeiro, Armando; Luís, Ricardo; Fernao Pires, VitorThe increase of electric vehicles creates several challenges to the electric grid, mainly in those with weak power or off-grid. DC microgrids are becoming more and more important in the context of renewable energy sources, where solar PV systems are dominant. In this paper is proposed the design of a DC system to charge electric vehicles using PV generation and a battery storage system. A single DC-DC converter is used to operate the solar PV array with maximum power point tracking method and controls power flow from PV to storage battery and to the EV, operating as DC EV charger. The operation under various loading conditions is discussed. The performance of the proposed solution was simulated using MATLAB/Simulink software.
- ESS design and management considering solar PV to fed off-grid EV chargerPublication . Santos, Diogo; Fonte, Pedro M; Pereira, Rita Marcos Fontes Murta; Barata, Filipe; Almeida, Paulo; Cordeiro, Armando; Luís, Ricardo Jorge Ferreira; Fernao Pires, VitorThe increase of electric vehicles creates several challenges to the electric grid, mainly in those with weak power or off-grid. DC microgrids are becoming more and more important in the context of renewable energy sources, where solar PV systems are dominant. In this paper is proposed the design of a DC system to charge electric vehicles using PV generation and a battery storage system. A single DC-DC converter is used to operate the solar PV array with maximum power point tracking method and controls power flow from PV to storage battery and to the EV, operating as DC EV charger. The operation under various loading conditions is discussed. The performance of the proposed solution was simulated using MATLAB/Simulink software.