Browsing by Author "Rodrigues, J."
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- Conversão de dióxido de carbono em combustíveis sintéticos renováveis, através de um processo eletroquímicoPublication . Guerra, Luís Filipe; Rodrigues, J.; Puna, Jaime; Gomes, João; Santos, Maria TeresaProjeto que contempla um processo eletroquímico inovador de produção de combustíveis sintéticos renováveis a partir da conversão de CO2; Tecnologia emergente alternativa aos processos termoquímicos de oxidação de carbono (steam reforming e gaseificação do carvão); Os principais combustíveis a ser produzidos por esta via são: metanol, metano, DME, entre outros.
- Geo-localization using indoor visible light communicationPublication . Louro, Paula; Vieira, Manuela; Vieira, Pedro; Rodrigues, J.; Lima, M. deNowadays, Global Positioning Systems (GPS) are used everywhere for positioning and navigation. However, its use is not suitable in indoor environment, due to power budget constraints and the strong attenuation inside buildings. Therefore, indoors navigation takes advantage of other technologies to infer position. Recently, several Visible Light Positioning (VLP) systems have been reported. Among these technologies, Visible Light Communication (VLC) is one of the most promising, as its operation is based on the use of LED lights, currently widely used in the illumination solutions of most buildings. In this paper, we propose an indoor navigation system based on VLC in an industrial application for automated warehouses, where the navigation of autonomous vehicles (AVG) is supported by VLC. The proposed VLC system establishes bidirectional communication between the infrastructure and the guided vehicles. LED transmitters at the warehouse ceiling support downlink data transmission from the Infrastructure to Vehicle (I2V). This channel provides positioning and navigation of the vehicles, as well as transmission of dedicated messages related to the requested tasks of the management warehouse system to the autonomous vehicles. The uplink channel from the Vehicle to the Infrastructure (V2I) is used to acknowledge the requested tasks and transmit updates on the concluded tasks. Optical transmitters are tri-chromatic white LEDs with a wide angle beam. The characterization of the optical transmitter system is done through MatLab simulations for path loss and VLC channel gain prediction, using the Lambertian model for the LED light distribution. Dedicated receivers based on a-SiC:H/a-Si:H photodiodes with selective spectral sensitivity are used to record the transmitted signal. The decoding strategy is based on accurate calibration of the output signal.
- Methane production by a combined Sabatier reaction/water electrolysis processPublication . Guerra, Luís; Rossi, S.; Rodrigues, J.; Gomes, João; Puna, Jaime; Santos, Maria TeresaThis paper describes production of synthesis gas (syngas) and its optimization through a one-step innovative 1 kW prototype of alkaline water electrolysis (patented), using graphite electrodes and without gas separation (containing CO, CO2, H2 and small amounts of O2). The behavior of the syngas composition and flow rate has been studied and optimized, changing operational parameters such as temperature, pressure and current intensity, and testing two different kinds of electrodes. Afterwards, the best syngas composition has been sent into a catalytic reactor (filled with a bed of Ni/CaO-Al2O3 catalyst) in order to achieve methane production, at 1 bar and different temperatures. The main competitive advantage of this process lies in the built-in of an innovative technology product, from renewable energy (RE) power in remote locations, such as islands, villages in mountains as an alternative for energy storage for mobility constraints. In the catalytic reactor it was possible to achieve a CH4 yield of 25.5 %, a CO2 conversion into CH4 of 44.2% and a CH4 selectivity of 96.5%.
- Preliminary study of synthesis gas production from water electrolysis, using the ELECTROFUEL (R) conceptPublication . Guerra, Luís; Gomes, João; Puna, Jaime; Rodrigues, J.This paper describes preliminary work on the generation of synthesis gas from water electrolysis using graphite electrodes without the separation of the generated gases. This is an innovative process, that has no similar work been done earlier. Preliminary tests allowed to establish correlations between the applied current to the electrolyser and flow rate and composition of the generated syngas, as well as a characterisation of generated carbon nanoparticles. The obtained syngas can further be used to produce synthetic liquid fuels, for example, methane, methanol or DME (dimethyl ether) in a catalytic reactor, in further stages of a present ongoing project, using the ELECTROFUEL® concept. The main competitive advantage of this project lies in the built-in of an innovative technology product, from RE (renewable energy) power in remote locations, for example, islands, villages in mountains as an alternative for energy storage for mobility constraints.
- Synthesis gas production from water electrolysis, using the Electrocracking conceptPublication . Guerra, Luís; Moura, K.; Rodrigues, J.; Gomes, João; Puna, Jaime; Bordado, João; Santos, Maria TeresaThe present research work is focused on the production of synthesis gas by water electrolysis, using renewable electric energy and, further on, liquefied biomass as a carbon source necessary for obtaining carbon monoxide and carbon dioxide. In order to demonstrate and also optimize this process, this study comprised the influence of the electrolyte concentration, liquefied cork concentration, temperature and pressure and the main process outputs, such as: the flow rate of the produced gas, carbon monoxide, carbon dioxide and oxygen composition, as well as the energy consumed in the process. This gas can further on, be used for producing renewable synthetic fuels, such as: methane, methanol, dimethyl ether (DME), diesel, etc. The optimum operational conditions thus determined for this process, at laboratory scale, comprised the use of NaOH 1.2 M mixed with 20% (v/v) liquefied cork, as electrolyte. Applying these operating conditions a synthesis gas composed of 66.67% H2, 25.32% CO, 0.00% CO2 and 8.01% O2 was obtained at a flow rate of 8.31 L/h, consuming a power of 7.75 Wh/L. Also, the analysis of the residual biomass deposited in the electrodes showed some changes in the initial structure, as expected.
- The 2014-15 eruption and the short-term geochemical evolution of the Fogo volcano (Cape Verde): evidence for small-scale mantle heterogeneityPublication . Mata, J.; Martins, S.; Mattielli, N.; Madeira, JFA; Faria, B.; Ramalho, R. S.; Silva, P.; Moreira, M; Caldeira, R.; Moreira, Mário; Rodrigues, J.; Martins, L.Recurrent eruptions at very active ocean island volcanoes provide the ideal means to gain insight on the scale of spatial variations at the mantle source and on temporal changes of magma genesis and evolution processes. In 2014, after 19 years of quiescence, Fogo volcano (Cape Verde Archipelago) experienced a new eruption, with the vents located 200 m from those of the 1995 eruption, and less than 2000 m from those of the 1951 event. This offered a unique opportunity to investigate the existence of small-scale mantle heterogeneities and the short-term compositional evolution of magmas erupted by a very active oceanic volcano like Fogo. Here we present petrological and geochemical data from the early stages of the Fogo's most recent eruption - started on November 23, 2014 - and compare them with the signature of previous eruptions (particularly those of 1995 and 1951). The magmas erupted in 2014 are alkaline (up to 23.4% and 0.94% of normative ne and lc, respectively) with somewhat evolved compositions (Mg # < 56), ranging from tephrites to phonotephrites. The eruption of phonotephritic lavas preceded the effusion of tephritic ones. Lavas carried to the surface clinopyroxene and kaersutite phenocrysts and cognate megacrysts, which indicate that the main stages of magma evolution occurred in magma chambers most probably located at mantle depths (25.6 5.5 km below sea level). This was followed by a shallower (<1.5 km below sea level) and shorter (approximate to 50 days) magma stagnation before the eruption. 2014 magmas have more unradiogenic Sr and more radiogenic Nd compositions than those of the previous 1951 and 1995 eruptions, which generally have less radiogenic Pb ratios. These isotopic differences- coming from quasi-coeval materials erupted almost in the same place- are remarkable and reflect the small-scale heterogeneity of the underlying mantle source. Moreover, they reflect the limited isotopic averaging of the source composition during partial melting events as well as the inefficient homogenization within the plumbing system when on route to the surface. The lid effect of an old and thick lithosphere is considered of utmost importance to the preservation of a significant part of source heterogeneity by erupted magmas. The decrease in the contribution of an enriched component to the Fogo magmas in the 2014 eruption marks a change on the volcano shortterm evolution that was characterized by a progressive increase of the importance of such a component. Nb/U ratios of the 2014 lavas are similar, within 2 sigma, to the mean value of OIB, but significantly lower than those reported for the 1995 and 1951 eruptions. This is considered to reflect the lack of significant mixing of the 2014 magmas with lithospheric melts, as opposed to what is here hypothesised for the two previous eruptions.
- Utilização de biomassa liquefeita na produção eletroquímica de gás de síntesePublication . Gonçalves, Ana Luísa; Guerra, Luís Filipe; Rodrigues, J.; Puna, Jaime; Gomes, João; Bordado, JoãoO presente trabalho de investigação visa, precisamente, a utilização de energias renováveis (solar ou eólica) no processo de eletrólise alcalina da água tendo como objetivo a produção de gás de síntese, com recurso a biomassa liquefeita como fonte de carbono, para uma posterior produção de biocombustíveis sintéticos.