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Advisor(s)
Abstract(s)
The hydrotris(pyrazol-1-yl)methane iron(II) complex [FeCl2{eta(3)-HC(pz)(3)}] (Fe, pz = pyrazol-1-yl) immobilized on commercial (MOR) or desilicated (MOR-D) zeolite, catalyses the oxidation of cyclohexane with hydrogen peroxide to cyclohexanol and cyclohexanone, under mild conditions. MOR-D/Fe (desilicated zeolite supported [FeCl2{eta(3)-HC(pz)(3)}] complex) provides an outstanding catalytic activity (TON up to 2.90 x 10(3)) with the concomitant overall yield of 38%, and can be easy recovered and reused. The MOR or MOR-D supported hydrotris(pyrazol-1-yl)methane iron(II) complex (MOR/Fe and MOR-D/Fe, respectively) was characterized by X-ray powder diffraction, ICP-AES, and TEM studies as well as by IR spectroscopy and N-2 adsorption at -196 degrees C. The catalytic operational conditions (e.g., reaction time, type and amount of oxidant, presence of acid and type of solvent) were optimized. (C) 2013 Elsevier B.V. All rights reserved.
Description
Keywords
C-scorpionates iron(II) Cyclohexane oxidation Supported catalysis Desilicated MOR zeolite Mild conditions Alkane oxidation Hydrocarbon oxygenations Aromatic-hydrocarbons Rhenium complexes Alkyl peroxides Ligands Acid H2O2 Cycloalkanes
Citation
MARTINS, L. M. D. R. S.; MARTINS, A.; ALEGRIA, E. C. B. A.; CARVALHO, A. P.; Pombeiro, A. J. L. - Efficient cyclohexane oxidation with hydrogen peroxide catalysed by a C-scorpionate iron(II) complex immobilized on desilicated MOR zeolite. Applied Catalysis A-General. ISSN 0926-860X. Vol. 464 (2013), p. 43-50.