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A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst

2012-11-05Journal article Open access
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dc.contributor.authorSutradhar, Manas
dc.contributor.authorKirillova, Marina V.
dc.contributor.authorGuedes Da Silva, M. Fátima C.
dc.contributor.authorMartins, Luisa
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2013-10-17T16:34:20Z
dc.date.available2013-10-17T16:34:20Z
dc.date.issued2012-11-05
dc.description.abstractThe new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions.por
dc.identifier.citationSUTRADHAR, Manas; KIRILLOVA, Marina V.; SILVA, M. Fátima C. Guedes da; MARTINS, Luísa M. D. R. S.; POMBEIRO, Armando J. L. - A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst. Inorganic Chemistry. ISSN: 0020-1669. Vol. 51, nr 21, (2012), p. 11229-11231.por
dc.identifier.issn0020-1669
dc.identifier.other10.1021/ic3017062
dc.identifier.urihttp://hdl.handle.net/10400.21/2745
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherAmer Chemical Socpor
dc.subjectHydrocarbon Oxygenationspor
dc.subjectVanadium Complexespor
dc.subjectCrystal-Structurepor
dc.subjectSolid-Statepor
dc.subjectLigandpor
dc.subject2-Naphtolspor
dc.subjectCompoundpor
dc.subjectCorepor
dc.subjectDFTpor
dc.titleA Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalystpor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceWashingtonpor
oaire.citation.endPage11231por
oaire.citation.issue21por
oaire.citation.startPage11229por
oaire.citation.titleInorganic Chemistrypor
oaire.citation.volume51por
person.familyNameSutradhar
person.familyNameKirillova
person.familyNameGuedes da Silva
person.familyNameMartins
person.familyNamePombeiro
person.givenNameManas
person.givenNameMarina V.
person.givenNameM. Fátima C.
person.givenNameLuisa
person.givenNameArmando
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person.identifier.orcid0000-0001-8323-888X
person.identifier.ridM-4089-2013
person.identifier.ridH-8274-2012
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person.identifier.ridI-5945-2012
person.identifier.scopus-author-id14053084900
person.identifier.scopus-author-id8526661400
person.identifier.scopus-author-id6701761571
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id7006067269
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
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