Publication
A fluorescente bicyclic Calix[4] Arene-Oxacyclophane with planar chirality: Resolution, chiroptical, properties, and absolute configuration.
| dc.contributor.author | Prata, José Virgílio | |
| dc.contributor.author | Costa, Alexandra | |
| dc.contributor.author | Pescitelli, Gennaro | |
| dc.contributor.author | Teixeira, Carlos M. | |
| dc.date.accessioned | 2015-08-24T09:41:36Z | |
| dc.date.available | 2015-08-24T09:41:36Z | |
| dc.date.issued | 2014-04-15 | |
| dc.description.abstract | A new inherently chiral calix[4]arene ICC 1 has been disclosed. The dissymmetry of 1 is generated from a chirality plane in the quinol moiety of a 1,3-bridged bicyclic calix[4]arene. ICC 1 has been resolved by enantioselective HPLC, and the chiroptical properties of both isolated antipodes (pS)-1 and (pR)-1 confirm their enantiomeric nature. The absolute configuration of the (pS)-1/(pR)-1 enantiomeric pair was established through time-dependent density functional theory (TDDFT) calculations of electronic circular dichroism (CD) spectra. (C) 2014 Elsevier Ltd. All rights reserved. | por |
| dc.identifier.citation | PRATA, José Virgílio Coelho; [et al] – A fluorescente bicyclic Calix[4] Arene-Oxacyclophane with planar chirality: Resolution, chiroptical, properties, and absolute configuration. Tetrahedron-Asymmetry. ISSN: 0957-4166. Vol. 25, nr. 6-7 (2014), pp. 547-553 | por |
| dc.identifier.doi | 10.1016/j.tetasy.2014.02.012 | |
| dc.identifier.issn | 0957-4166 | |
| dc.identifier.uri | http://hdl.handle.net/10400.21/4920 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Pergamon-Elsevier Science LTD | por |
| dc.relation.publisherversion | http://www.sciencedirect.com/science/article/pii/S0957416614000925# | |
| dc.subject | Ray Molecular-Structures | por |
| dc.subject | Calixarenes | por |
| dc.title | A fluorescente bicyclic Calix[4] Arene-Oxacyclophane with planar chirality: Resolution, chiroptical, properties, and absolute configuration. | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 553 | por |
| oaire.citation.issue | 6-7 | por |
| oaire.citation.startPage | 547 | por |
| oaire.citation.title | Tetrahedron-Asymmetry | por |
| oaire.citation.volume | 25 | por |
| person.familyName | Prata | |
| person.familyName | Costa | |
| person.givenName | José Virgílio | |
| person.givenName | Alexandra | |
| person.identifier | 191765 | |
| person.identifier.ciencia-id | C11A-9130-8981 | |
| person.identifier.ciencia-id | 4212-F7BF-D971 | |
| person.identifier.orcid | 0000-0002-9068-2847 | |
| person.identifier.orcid | 0000-0002-5518-6506 | |
| person.identifier.rid | B-7214-2008 | |
| person.identifier.scopus-author-id | 9276778400 | |
| person.identifier.scopus-author-id | 8968446100 | |
| rcaap.rights | closedAccess | por |
| rcaap.type | article | por |
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| relation.isAuthorOfPublication.latestForDiscovery | 5f3891cc-260d-41d3-b803-4fd17e3734bd |