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Nematic wetting and filling of crenellated surfaces

dc.contributor.authorSilvestre, N. M.
dc.contributor.authorEskandari, Z.
dc.contributor.authorPatricio, Pedro
dc.contributor.authorRomero-Enrique, J. M.
dc.contributor.authorTelo da Gama, M. M.
dc.date.accessioned2012-09-11T16:18:21Z
dc.date.available2012-09-11T16:18:21Z
dc.date.issued2012-07-09
dc.description.abstractWe investigate nematic wetting and filling transitions of crenellated surfaces (rectangular gratings) by numerical minimization of the Landau-de Gennes free energy as a function of the anchoring strength, for a wide range of the surface geometrical parameters: depth, width, and separation of the crenels. We have found a rich phase behavior that depends in detail on the combination of the surface parameters. By comparison to simple fluids, which undergo a continuous filling or unbending transition, where the surface changes from a dry to a filled state, followed by a wetting or unbinding transition, where the thickness of the adsorbed fluid becomes macroscopic and the interface unbinds from the surface, nematics at crenellated surfaces reveal an intriguingly rich behavior: in shallow crenels only wetting is observed, while in deep crenels, only filling transitions occur; for intermediate surface geometrical parameters, a new class of filled states is found, characterized by bent isotropic-nematic interfaces, which persist for surfaces structured on large scales, compared to the nematic correlation length. The global phase diagram displays two wet and four filled states, all separated by first-order transitions. For crenels in the intermediate regime re-entrant filling transitions driven by the anchoring strength are observed.por
dc.identifier.citationSilvestre N M, Eskandari Z, Patricio P, Romero-Enrique J M, Telo da Gama M M. Nematic wetting and filling of crenellated surfaces.Physical Review E. 2012: 86 (1).por
dc.identifier.issn1539-3755
dc.identifier.urihttp://hdl.handle.net/10400.21/1776
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherAmer Physical Socpor
dc.relation.ispartofseries;011703
dc.subjectLiquid-Crystal Alignmentpor
dc.subjectPhase-Transitionpor
dc.subjectSubstratepor
dc.subjectAdsorptionpor
dc.subjectGeometrypor
dc.subjectLayerpor
dc.titleNematic wetting and filling of crenellated surfacespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceUSApor
oaire.citation.issue1por
oaire.citation.titlePhysical Review Epor
oaire.citation.volume86por
person.familyNamePatricio
person.givenNamePedro
person.identifier.ciencia-idC616-BA77-E9C9
person.identifier.orcid0000-0002-9050-9956
person.identifier.ridA-2750-2009
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication11a2a1d5-8165-475a-8a54-e32bd8e8ce4e
relation.isAuthorOfPublication.latestForDiscovery11a2a1d5-8165-475a-8a54-e32bd8e8ce4e

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