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Baeyer-Villiger oxidation of Keotones catalysed by rhenium complexes bearing N- Or Oxo-Ligands

2012-11-07Journal article Restricted access
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dc.contributor.authorAlegria, Elisabete
dc.contributor.authorMartins, Luisa
dc.contributor.authorKirillova, Marina V.
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2015-09-08T13:42:59Z
dc.date.available2015-09-08T13:42:59Z
dc.date.issued2012-11-07
dc.description.abstractRhenium (I, III-V or VII) complexes bearing N-donor or oxo-ligands catalyse the Baeyer-Villiger oxidation of cyclic and linear ketones (e.g. 2-methylcyclohexanone, 2-methylcyclopentanone, cyclohexanone, cyclopentanone, cyclobutanone and 3,3-dimethyl-2-butanone) into the corresponding lactones or esters, in the presence of aqueous H2O2 (30%). The effects of various reaction parameters are studied allowing to achieve yields up to 54%.por
dc.identifier.citationAlegria, E. C. B. A.; [et al] – Baeyer-Villiger oxidation of Keotones catalysed by rhenium complexes bearing N- Or Oxo-Ligands. Applied Catalysis A-General. ISSN: 0926-860X. Vol. 443 (2012), pp. 27-32por
dc.identifier.doi10.1016/j.apcata.2012.07.007
dc.identifier.issn0926-860X
dc.identifier.urihttp://hdl.handle.net/10400.21/5095
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevier Science BVpor
dc.relationFundação para a Ciência e a Tecnologia - PTDC/QUIQUI/102150/2008
dc.relationFundação para a Ciência e a Tecnologia - PTDC-EQU-EQU-122025-2010
dc.relationFundação para a Ciência e a Tecnologia - PEst-OE/QUI/U10100/2011
dc.subjectBaeyer-Villiger Oxidationpor
dc.subjectHydrogen Peroxidepor
dc.subjectRhenium Complexespor
dc.subjectHomogeneous Catalysispor
dc.subjectKetonespor
dc.subjectLactonespor
dc.subjectC-Scorpionatespor
dc.subjectPyrazolepor
dc.subjectPT-II catalysts
dc.subjectHydrogen-peroxide
dc.subjectMolecular-oxygen
dc.subjectIonic liquids
dc.subjectLactone hydrolysis
dc.subjectMetal-catalysts
dc.subjectLewis acidity
dc.subjectPlatinum(II)
dc.subjectPalladium(II)
dc.subjectCyclohexanone
dc.titleBaeyer-Villiger oxidation of Keotones catalysed by rhenium complexes bearing N- Or Oxo-Ligandspor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceAmsterdam
oaire.citation.endPage32por
oaire.citation.startPage27por
oaire.citation.titleApplied Catalysis A-Generalpor
oaire.citation.volume443por
person.familyNameAlegria
person.familyNameMartins
person.familyNameKirillova
person.familyNamePombeiro
person.givenNameElisabete
person.givenNameLuisa
person.givenNameMarina V.
person.givenNameArmando
person.identifier863202
person.identifier637885
person.identifier.ciencia-id8C1F-851A-9F1C
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.ciencia-id921F-C685-1674
person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0003-4060-1057
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0002-4375-828X
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridE-9945-2012
person.identifier.ridG-6210-2011
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id8315848300
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id8526661400
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspor
rcaap.typearticlepor
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