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Metal-organic frameworks with pyridyl-based isophthalic acid and their catalytic applications in microwave assisted peroxidative oxidation of alcohols and Henry reaction

2016-04Journal article Restricted access
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dc.contributor.authorKarmakar, Anirban
dc.contributor.authorMartins, Luisa
dc.contributor.authorHAZRA, SUSANTA
dc.contributor.authorGuedes Da Silva, M. Fátima C.
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2019-02-25T11:56:22Z
dc.date.available2019-02-25T11:56:22Z
dc.date.issued2016-04
dc.description.abstractReactions of 5-{(pyridin-4-ylmethyl)amino} isophthalic acid (H(2)L1) with copper(II), zinc(II), and cadmium(II) were studied, and the obtained metal organic frameworks (MOFs) [{Cu(L1)(DMF)}center dot DMF center dot H2O](n) (1), [Zn(L1)(H2O)(n) (2), and [Cd(L1)](n) (3) were characterized by elemental analysis, Fourier transform infrared spectroscopy, and X-ray single-crystal diffraction. As shown by X-ray crystallography, novel hybrid organic inorganic coordination-driven assemblies were obtained which exhibit different two- and three-dimensional (2D and 3D) polymeric architectures. Compounds 1 and 2 have 2D structures, whereas compound 3 features a 3D network type polymer with a dimetallic core acting as a secondary building unit. These frameworks act as heterogeneous polymeric solid catalysts (the most effective one being the copper MOF 1) for solvent-free microwave assisted peroxidative oxidation of primary and secondary alcohols. They also effectively catalyze the nitroaldol (Henry) reaction of different aldehydes with nitroalkanes in water. These MOF-based heterogeneous catalysts can be easily recovered and reused, at least for a few consecutive cycles, without losing activity.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationKARMAKAR, Anirban; [et al] – Metal-organic frameworks with pyridyl-based isophthalic acid and their catalytic applications in microwave assisted peroxidative oxidation of alcohols and Henry reaction. Crystal Growth & Design. ISSN 1528-7483. Vol. 16, N.º 4 (2016), pp. 1837-1849pt_PT
dc.identifier.doi10.1021/acs.cgd.5b01178pt_PT
dc.identifier.issn1528-7483
dc.identifier.issn1528-7505
dc.identifier.urihttp://hdl.handle.net/10400.21/9587
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherAmerican Chemical Societypt_PT
dc.relationUID/QUI/UI0100/2013 - FCTpt_PT
dc.relationSYNTHESIS OF NANOPOROUS HOMOCHIRAL METAL-ORGANIC FRAMEWORKS AND THEIR APPLICATION IN ENANTIOSELECTIVE CATALYSIS
dc.relation.publisherversionhttps://pubs.acs.org/doi/ipdf/10.1021/acs.cgd.5b01178pt_PT
dc.subjectIsophthalic acidpt_PT
dc.subjectMetal organic frameworks (MOFs)pt_PT
dc.subjectMicrowave assisted peroxidativept_PT
dc.titleMetal-organic frameworks with pyridyl-based isophthalic acid and their catalytic applications in microwave assisted peroxidative oxidation of alcohols and Henry reactionpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleSYNTHESIS OF NANOPOROUS HOMOCHIRAL METAL-ORGANIC FRAMEWORKS AND THEIR APPLICATION IN ENANTIOSELECTIVE CATALYSIS
oaire.awardURIinfo:eu-repo/grantAgreement/FCT//SFRH%2FBPD%2F76192%2F2011/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F78264%2F2011/PT
oaire.citation.endPage1849pt_PT
oaire.citation.issue4pt_PT
oaire.citation.startPage1837pt_PT
oaire.citation.titleCrystal Growth and Designpt_PT
oaire.citation.volume16pt_PT
oaire.fundingStreamSFRH
person.familyNameKarmakar
person.familyNameMartins
person.familyNameHAZRA
person.familyNameGuedes da Silva
person.familyNamePombeiro
person.givenNameAnirban
person.givenNameLuisa
person.givenNameSUSANTA
person.givenNameM. Fátima C.
person.givenNameArmando
person.identifier637885
person.identifier-5yoR4sAAAAJ&hl=en
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person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0003-3047-2204
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0002-8101-2016
person.identifier.orcid0000-0003-4836-2409
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridG-3990-2012
person.identifier.ridG-6210-2011
person.identifier.ridH-8274-2012
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id14037235600
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id23481611800
person.identifier.scopus-author-id6701761571
person.identifier.scopus-author-id7006067269
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
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