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Influence of processing conditions on the morphological and mechanical properties of compatibilized PP/LCP blends

dc.contributor.authorFilipe, Susana
dc.contributor.authorMaia, João Manuel
dc.contributor.authorLeal, Catarina R.
dc.contributor.authorCidade, Maria Teresa
dc.date.accessioned2023-05-30T07:36:30Z
dc.date.available2023-05-30T07:36:30Z
dc.date.issued2007-08
dc.description.abstractThe main aim of this work is to study theinfluence of the application of different processing conditionson the morphological and mechanical properties of thermo-plastic/LCP blends, in which the viscosity ratios are inferiorto unity and decrease with increasing temperature. The waythe microstructure evolves along the extruder determines thefinal morphology and thus, the mechanical performance ofthe systems. In the present case, the mechanical properties arerelated with the degree of fibrillation in the final composites.The best degree of fibrillation was obtained for low screwspeeds and temperatures and for intermediate outputs. Theuse of high screw speeds and processing temperatures resultsin a decrease of the viscosity ratio, in the former case via anincrease in the viscous dissipation, at the regions of highershear rates (kneading-elements). The application of a lowerprocessing temperature is advantageous for deformation,break-up, and fibrillar formation because of the higher viscos-ity ratios and higher shear stresses involved.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationFILIPE, Susana; [et al] – Influence of processing conditions on the morphological and mechanical properties of compatibilized PP/LCP blends. Journal of Applied Polymer Science. ISSN 1097-4628. Vol. 105, N.º 3 (2007), pp. 1521-1532.pt_PT
dc.identifier.doi10.1002/app.26412pt_PT
dc.identifier.eissn1097-4628
dc.identifier.urihttp://hdl.handle.net/10400.21/16166
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherWiley Online Librarypt_PT
dc.relationPOCTI/CTM/32658/99 - FCTpt_PT
dc.subjectLiquid crystalline polymerspt_PT
dc.subjectThermoplasticpt_PT
dc.subjectBlendspt_PT
dc.subjectProcessing conditionspt_PT
dc.subjectIsotactic polyproylenept_PT
dc.titleInfluence of processing conditions on the morphological and mechanical properties of compatibilized PP/LCP blendspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage1532pt_PT
oaire.citation.issue3pt_PT
oaire.citation.startPage1521pt_PT
oaire.citation.titleJournal of Applied Polymer Sciencept_PT
oaire.citation.volume105pt_PT
person.familyNameMarques Mendes Almeida da Rosa Leal
person.givenNameCatarina
person.identifierA-2814-2009
person.identifier.ciencia-idAF15-486E-BB15
person.identifier.orcid0000-0001-5871-4936
person.identifier.scopus-author-id7005379280
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication4db8990d-5eb1-4515-ae7a-68873cf776a5
relation.isAuthorOfPublication.latestForDiscovery4db8990d-5eb1-4515-ae7a-68873cf776a5

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