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Electrochemical properties of (H5-C5Me5)-rhodium and – iridium complexes Bis(pyrazolyl)alkane ligands

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dc.contributor.authorMartins, Luisa
dc.contributor.authorPettinari, Claudio
dc.contributor.authorMarchetti, Fábio
dc.contributor.authorAlegria, Elisabete
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2015-08-24T11:14:30Z
dc.date.available2015-08-24T11:14:30Z
dc.date.issued2014
dc.description.abstractThe electrochemical properties of rhodium(III) 1-3 and iridium(III) 4-6 complexes containing bis(pyrazolyl)alkane ligands [MCp*Cl(R2C(3,5-R'2pz)2)]X (M = Rh (1) or Ir (4), R = R' = H, X = Cl; M = Rh (2) or Ir (5), R=H,R'=Me,X=Cl;M=Rh(3) or Ir (6), R=Me,R'=H,X=OTf;pz=pyrazolyl;Cp*=η5-C5Me5) were investigated by cyclic voltammetry and controlled potential electrolysis. They exhibit two sequential irreversible reductions assigned to the MIII → MII and MII → MI reductions, which are dependent on the methylation of the bis(pyrazolyl)alkane ligands.por
dc.identifier.citationMARTINS, Luísa Margarida; [et al] – Electrochemical properties of (H5-C5Me5)-Rhodium and – Iridium complexes Bis(pyrazolyl)alkane ligands. Portugaliae Electrochimica Acta. ISSN: 1647-1571. Vol. 32, nr. 4 (2014), pp. 253-257por
dc.identifier.doi10.4152/pea.201404253
dc.identifier.issn1647-1571
dc.identifier.urihttp://hdl.handle.net/10400.21/4938
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherPortuguese Electrochemical Societypor
dc.subjectBis(pyrazolyl)alkanepor
dc.subjectRhodium(III) and Iridium(III) Complexespor
dc.subjectCyclic Voltammetrypor
dc.subjectControlled Potential Electrolysispor
dc.titleElectrochemical properties of (H5-C5Me5)-rhodium and – iridium complexes Bis(pyrazolyl)alkane ligandspor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceCoimbrapor
oaire.citation.endPage257por
oaire.citation.issue4por
oaire.citation.startPage253por
oaire.citation.titlePortugaliae Electrochimica Actapor
oaire.citation.volume32por
person.familyNameMartins
person.familyNamePettinari
person.familyNameAlegria
person.familyNamePombeiro
person.givenNameLuisa
person.givenNameClaudio
person.givenNameElisabete
person.givenNameArmando
person.identifier637885
person.identifier863202
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.ciencia-id8C1F-851A-9F1C
person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0002-2547-7206
person.identifier.orcid0000-0003-4060-1057
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridG-6210-2011
person.identifier.ridE-9945-2012
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id7006581579
person.identifier.scopus-author-id8315848300
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication8ed70b09-b4d3-4a5d-9f75-12b13a332204
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relation.isAuthorOfPublication.latestForDiscovery6d781c38-c45e-4159-b795-8c8675606160

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