Publication
Communication: Re-entrant limits of stability of the liquid phase and the Speedy scenario in colloidal model systems
| dc.contributor.author | Rovigatti, Lorenzo | |
| dc.contributor.author | Bianco, Valentino | |
| dc.contributor.author | Tavares, Jose | |
| dc.contributor.author | SCIORTINO, Francesco | |
| dc.date.accessioned | 2017-02-20T14:49:11Z | |
| dc.date.available | 2017-02-20T14:49:11Z | |
| dc.date.issued | 2017-01-28 | |
| dc.description.abstract | A re-entrant gas-liquid spinodal was proposed as a possible explanation of the apparent divergence of the compressibility and specific heat off supercooling water. Such a counter-intuitive possibility, e.g., a liquid that becomes unstable to gas-like fluctuations on cooling at positive pressure, has never been observed, neither in real substances nor in off-lattice simulations. More recently, such a re-entrant scenario has been dismissed on the premise that the re-entrant spinodal would collide with the gas-liquid coexisting curve (binodal) in the pressure-temperature plane. Here we study, numerically and analytically, two previously introduced one-component patchy particle models that both show (i) a re-entrant limit of stability of the liquid phase and (ii) a re-entrant binodal, providing a neat in silico (and in charta) realization of such unconventional thermodynamic scenario. | pt_PT |
| dc.description.version | info:eu-repo/semantics/publishedVersion | pt_PT |
| dc.identifier.citation | ROVIGATTI, Lorenzo; [et al] – Communication: Re-entrant limits of stability of the liquid phase and the Speedy scenario in colloidal model systems. American Institute of Physics – The Journal of Chemical Physics. ISSN 0021-9606. Vol. 146, N.º 4 (2017), pp. 1-6 | pt_PT |
| dc.identifier.doi | http://dx.doi.org/10.1063/1.4974830 | pt_PT |
| dc.identifier.issn | 0021-9606 | |
| dc.identifier.issn | 1089-7690 | |
| dc.identifier.uri | http://hdl.handle.net/10400.21/6831 | |
| dc.language.iso | eng | pt_PT |
| dc.peerreviewed | yes | pt_PT |
| dc.publisher | AIP Publishing | pt_PT |
| dc.relation.publisherversion | http://aip.scitation.org/doi/10.1063/1.4974830 | pt_PT |
| dc.title | Communication: Re-entrant limits of stability of the liquid phase and the Speedy scenario in colloidal model systems | pt_PT |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.issue | 4 | pt_PT |
| oaire.citation.title | The Journal of Chemical Physics | pt_PT |
| oaire.citation.volume | 146 | pt_PT |
| person.familyName | Rovigatti | |
| person.familyName | Bianco | |
| person.familyName | Tavares | |
| person.familyName | SCIORTINO | |
| person.givenName | Lorenzo | |
| person.givenName | Valentino | |
| person.givenName | Jose | |
| person.givenName | Francesco | |
| person.identifier.ciencia-id | 371D-51C6-975C | |
| person.identifier.orcid | 0000-0001-5017-2829 | |
| person.identifier.orcid | 0000-0003-3844-6406 | |
| person.identifier.orcid | 0000-0002-1509-9707 | |
| person.identifier.orcid | 0000-0002-2418-2713 | |
| person.identifier.rid | A-2891-2009 | |
| person.identifier.scopus-author-id | 35621140500 | |
| person.identifier.scopus-author-id | 7005775345 | |
| rcaap.rights | openAccess | pt_PT |
| rcaap.type | article | pt_PT |
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