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Advances on the development of novel heterogeneous catalysts for transesterification of triglycerides in biodiesel

dc.contributor.authorPuna, Jaime
dc.contributor.authorGomes, João
dc.contributor.authorCorreia, M. Joana N.
dc.contributor.authorDias, A. P. Soares
dc.contributor.authorBordado, J. C.
dc.date.accessioned2011-11-30T11:22:39Z
dc.date.available2011-11-30T11:22:39Z
dc.date.issued2010-11
dc.description.abstractThis paper describes experimental work done towards the search for more profitable and sustainable alternatives regarding biodiesel production, using heterogeneous catalysts instead of the conventional homogenous alkaline catalysts, such as NaOH, KOH or sodium methoxide, for the methanolysis reaction. This experimental work is a first stage on the development and optimization of new solid catalysts, able to produce biodiesel from vegetable oils. The heterogeneous catalytic process has many differences from the currently used in industry homogeneous process. The main advantage is that, it requires lower investment costs, since no need for separation steps of methanol/catalyst, biodiesel/catalyst and glycerine/catalyst. This work resulted in the selection of CaO and CaO modified with Li catalysts, which showed very good catalytic performances with high activity and stability. In fact FAME yields higher than 92% were observed in two consecutive reaction batches without expensive intermediate reactivation procedures. Therefore, those catalysts appear to be suitable for biodiesel production.por
dc.identifier.citationPuna J F, Gomes J F, Correia M J N, Dias A P S, Bordado J C.Advances on the development of novel heterogeneous catalysts for transesterification of triglycerides in biodiesel. Fuel. 2010; 89 (11): 3602-3606.por
dc.identifier.issn0016-2361
dc.identifier.urihttp://hdl.handle.net/10400.21/739
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevier SCI LTDpor
dc.relation.ispartofseries11;
dc.subjectBiodieselpor
dc.subjectHeterogeneous catalystspor
dc.subjectTransesterificationpor
dc.titleAdvances on the development of novel heterogeneous catalysts for transesterification of triglycerides in biodieselpor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceOxonpor
oaire.citation.endPage3606por
oaire.citation.issue89por
oaire.citation.startPage3602por
oaire.citation.titleFuelpor
person.familyNamePuna
person.familyNameGomes
person.givenNameJaime
person.givenNameJoão
person.identifier790253
person.identifier60203
person.identifier.ciencia-idEE14-5CB2-AF04
person.identifier.ciencia-id0212-E6D6-566C
person.identifier.orcid0000-0002-2763-3655
person.identifier.orcid0000-0003-2579-6669
person.identifier.ridA-6442-2011
person.identifier.scopus-author-id24402152700
person.identifier.scopus-author-id56113031900
rcaap.rightsrestrictedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublicationcc1ba86f-9699-4622-a467-dece54231697
relation.isAuthorOfPublicatione44cd72e-bcbb-4612-a274-60cb1915bc0c
relation.isAuthorOfPublication.latestForDiscoverycc1ba86f-9699-4622-a467-dece54231697

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