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Zeolites and related materials as catalyst supports for hydrocarbon oxidation reactions

2022-01-26Journal article Open access
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dc.contributor.authorMartins, Angela
dc.contributor.authorNunes, Nelson
dc.contributor.authorCarvalho, Ana P.
dc.contributor.authorMartins, Luisa
dc.date.accessioned2023-05-16T09:53:02Z
dc.date.available2023-05-16T09:53:02Z
dc.date.issued2022-01-26
dc.description.abstractCatalytic oxidation is a key technology for the conversion of petroleum-based feedstocks into useful chemicals (e.g., adipic acid, caprolactam, glycols, acrylates, and vinyl acetate) since this chemical transformation is always involved in synthesis processes. Millions of tons of these compounds are annually produced worldwide and find applications in all areas of chemical industries, ranging from pharmaceutical to large-scale commodities. The traditional industrial methods to produce large amounts of those compounds involve over-stoichiometric quantities of toxic inorganic reactants and homogeneous catalysts that operate at high temperature, originating large amounts of effluents, often leading to expensive downstream processes, along with nonrecovery of valuable catalysts that are loss within the reactant effluent. Due to the increasingly stringent environmental legislation nowadays, there is considerable pressure to replace these antiquate technologies, focusing on heterogeneous catalysts that can operate under mild reactions conditions, easily recovered, and reused. Parallelly, recent advances in the synthesis and characterization of metal complexes and metal clusters on support surfaces have brought new insights to catalysis and highlight ways to systematic catalysts design. This review aims to provide a comprehensive bibliographic examination over the last 10 years on the development of heterogeneous catalysts, i.e., organometallic complexes or metal clusters immobilized in distinct inorganic supports such as zeolites, hierarchical zeolites, silicas, and clays. The methodologies used to prepare and/or modify the supports are critically reviewed, as well as the methods used for the immobilization of the active species. The applications of the heterogenized catalysts are presented, and some case-studies are discussed in detail.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationMARTINS, Ângela; [et al] – Zeolites and related materials as catalyst supports for hydrocarbon oxidation reactions. Catalysts. eISSN 2073-4344. Vol. 12, N.º 2 (2022), pp. 1-52.pt_PT
dc.identifier.doi10.3390/catal12020154pt_PT
dc.identifier.eissn2073-4344
dc.identifier.urihttp://hdl.handle.net/10400.21/16039
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherMDPIpt_PT
dc.relationLA/P/0056/2020 - FCTpt_PT
dc.relationCentro de Química Estrutural
dc.relationCentro de Química Estrutural
dc.relation.publisherversionhttps://www.mdpi.com/2073-4344/12/2/154pt_PT
dc.subjectHydrocarbon oxidation reactionspt_PT
dc.subjectZeolitespt_PT
dc.subjectHierarchical zeolitespt_PT
dc.subjectMesoporous silicaspt_PT
dc.subjectImmobilized catalystpt_PT
dc.subjectOrganometallic complexespt_PT
dc.subjectMetal particlespt_PT
dc.subjectAlkanespt_PT
dc.subjectAlkenespt_PT
dc.subjectAromatic substratept_PT
dc.titleZeolites and related materials as catalyst supports for hydrocarbon oxidation reactionspt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleCentro de Química Estrutural
oaire.awardTitleCentro de Química Estrutural
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00100%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00100%2F2020/PT
oaire.citation.endPage52pt_PT
oaire.citation.issue2pt_PT
oaire.citation.startPage1pt_PT
oaire.citation.titleCatalystspt_PT
oaire.citation.volume12pt_PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
person.familyNameMartins
person.familyNameNunes
person.familyNameCarvalho
person.familyNameMartins
person.givenNameAngela
person.givenNameNelson
person.givenNameAna
person.givenNameLuisa
person.identifier1344292
person.identifierK-5479-2013
person.identifier637885
person.identifier.ciencia-id781F-79D3-9070
person.identifier.ciencia-id1B16-7872-5A09
person.identifier.ciencia-id6F1E-301F-71BA
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.orcid0000-0003-1637-478X
person.identifier.orcid0000-0003-4499-0379
person.identifier.orcid0000-0001-5967-4200
person.identifier.orcid0000-0002-5403-9352
person.identifier.ridB-1775-2012
person.identifier.ridA-8516-2012
person.identifier.ridK-5479-2013
person.identifier.ridG-6210-2011
person.identifier.scopus-author-id7203013509
person.identifier.scopus-author-id11540776800
person.identifier.scopus-author-id36855267200
person.identifier.scopus-author-id8650947800
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccesspt_PT
rcaap.typearticlept_PT
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