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Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]

2017-03-29Journal article Restricted access
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dc.contributor.authorMendes, Marta
dc.contributor.authorDa Costa Ribeiro, Ana Paula
dc.contributor.authorAlegria, Elisabete
dc.contributor.authorMartins, Luisa
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2017-05-09T10:29:15Z
dc.date.available2017-05-09T10:29:15Z
dc.date.issued2017-03-29
dc.description.abstractA simple and mild (room temperature) process for oxidation of o-, m- or p-xylene to the corresponding methylbenzyl alcohols, tolualdehydes and toluic acids, using H2O2 (30% aqueous solution) and the iron(II) C-scorpionate [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) catalyst is presented. Remarkably, after 5 min of reaction an overall oxygenates yield of 22% (TOF = 1.3 × 102 h−1) was obtained. The effects of reaction parameters, such as reaction time, temperature, amount of catalyst, type and amount of oxidant are reported and discussed.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationMENDES, Marta; [et al] – Liquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]. Polyhedron. ISSN . Vol. 125 (2017), pp. 151-155pt_PT
dc.identifier.doihttps://doi.org/10.1016/j.poly.2016.10.037pt_PT
dc.identifier.issn0277-5387
dc.identifier.urihttp://hdl.handle.net/10400.21/6990
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relation.publisherversionhttp://ac.els-cdn.com/S0277538716305344/1-s2.0-S0277538716305344-main.pdf?_tid=524c0fde-34a1-11e7-83bf-00000aacb35d&acdnat=1494325493_ab243e4e93b2be0233772ee9c233741ept_PT
dc.subjectXylenept_PT
dc.subjectOxidationpt_PT
dc.subjectScorpionatept_PT
dc.subjectIronpt_PT
dc.subjectHydrogen peroxidept_PT
dc.titleLiquid phase oxidation of xylenes catalyzed by the tripodal C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)(3)}]pt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage155pt_PT
oaire.citation.startPage151pt_PT
oaire.citation.titlePolyhedronpt_PT
oaire.citation.volume125pt_PT
person.familyNameda Costa Ribeiro
person.familyNameAlegria
person.familyNameMartins
person.familyNamePombeiro
person.givenNameAna Paula
person.givenNameElisabete
person.givenNameLuisa
person.givenNameArmando
person.identifier1336277
person.identifier863202
person.identifier637885
person.identifier.ciencia-idE115-5C31-30F4
person.identifier.ciencia-id8C1F-851A-9F1C
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0003-4323-4328
person.identifier.orcid0000-0003-4060-1057
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridF-8341-2014
person.identifier.ridE-9945-2012
person.identifier.ridG-6210-2011
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id22235818800
person.identifier.scopus-author-id8315848300
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublicationebe0b25e-d8b0-4c6a-ab27-91f199d36347
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