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Reactivity of bulky tris(Phenylpyrazolyl) methanesulfonate copper(I) complexes towards small unsaturated molecules

2012-09Journal article Restricted access
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dc.contributor.authorRocha, Bruno G. M.
dc.contributor.authorWanke, Riccardo
dc.contributor.authorSilva, Maria de Fátima Costa Guedes da
dc.contributor.authorLuzyanin, Konstantin V.
dc.contributor.authorMartins, Luisa
dc.contributor.authorSmolenski, Piotr
dc.contributor.authorA.J.L. Pombeiro
dc.date.accessioned2015-09-08T15:22:34Z
dc.date.available2015-09-08T15:22:34Z
dc.date.issued2012-09
dc.description.abstractReaction of the tris(3-phenylpyrazolyl)methane sulfonate species (Tpms(Ph))Li with the copper(I) complex [Cu(MeCN)(4)][PF6] affords [Cu(Tpms(Ph))(MeCN)] 1. The latter, upon reaction with equimolar amounts of cyclohexyl-(CyNC) or 2,6-dimethylphenyl (XylNC) isocyanides, or excess CO, furnishes the corresponding Cu(I)complexes [Cu(Tpms(Ph))(CNR)] (R = Cy 2, Xyl 3) or [Cu(Tpms(Ph))(CO)] 4. The ligated isocyanide in 2 or 3 (or the acetonitrile ligand in 1)is displaced by 3-iminoisoindolin-1-one to afford 5, the first copper(I) complex containing an 3-iminoisoindolin-1-one ligand. The ligated acetonitrile in 1 undergoes nucleophilic attack by methylamine to give the amidine complex [Cu(Tpms(Ph)){MeC(NH)NHMe}] 6, whereas only the starting materials were recovered from the attempted corresponding reactions of 2 and 3 with methylamine. Complexes 1 or 6 form the trinuclear hydroxo-copper(II)species [(mu-Cu){Cu(mu-OH) (2)(Tpms(Ph))}(2)] 7 upon air oxidation in moist methanol. In all the complexes the scorpionate ligand facially caps the metal in the N,N,O-coordination mode.por
dc.identifier.citationROCHA, B. G. M.; [et al] – Reactivity of bulky tris(Phenylpyrazolyl) methanesulfonate copper(I) complexes towards small unsaturated molecules. Journal of Organometallic Chemistry. ISSN: 0022-328X. Vol. 714 (2012)por
dc.identifier.doi10.1016/j.jorganchem.2012.03.022
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10400.21/5119
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevierpor
dc.relationFundação para a Ciência e a Tecnologia (FCT), Portugal
dc.relationPPCDT program (FEDER) - PTDC/QUI-QUI/102150/2008
dc.relationPPCDT program (FEDER) - PTDC/QUI-QUI/098760/2008
dc.relationPPCDT program (FEDER) - PTDC/QUI-QUI/109846/2009
dc.relationPPCDT program (FEDER) - PEst-OE/QUI/UI0100/2011
dc.relationGroup V of Centro de Química Estrutural - SFRH/BD/23187/2005
dc.relationGroup V of Centro de Química Estrutural - BL-CQE/2010-014
dc.relationInstituto Superior Técnico (IST)
dc.subjectTris(pyrazolyl)methanesulfonate ligandpor
dc.subjectCopper complexespor
dc.subjectIsocyanidepor
dc.subjectCarbon monoxidepor
dc.subjectIminoisoindolin-1-Onepor
dc.subjectCatalytic peroxidative oxidation
dc.subjectCoordination chemistry
dc.subjectRhenium complexes
dc.subjectMild conditions
dc.subjectTriazapentadienato complexes
dc.subjectStructural-characterization
dc.subjectSpectroscopic properties
dc.subjectCyclohexane oxidation
dc.subjectCrystal-structures
dc.subjectRedox properties
dc.titleReactivity of bulky tris(Phenylpyrazolyl) methanesulfonate copper(I) complexes towards small unsaturated moleculespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.conferencePlaceLausanne
oaire.citation.titleJournal of Organometallic Chemistrypor
oaire.citation.volume714por
person.familyNameWanke
person.familyNameMartins
person.familyNameSmolenski
person.familyNamePombeiro
person.givenNameRiccardo
person.givenNameLuisa
person.givenNamePiotr
person.givenNameArmando
person.identifier637885
person.identifier772058
person.identifier.ciencia-idE611-325F-1931
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.ciencia-id3119-4D49-A268
person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0002-5480-7905
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0001-5969-6012
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridG-6210-2011
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id23091814400
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication65993438-6a74-4b50-b047-3874069290eb
relation.isAuthorOfPublication8ed70b09-b4d3-4a5d-9f75-12b13a332204
relation.isAuthorOfPublication462852fa-ba94-4430-a4f9-ba1a1a22e130
relation.isAuthorOfPublication6d18ff2e-5c33-4010-b1e7-964c72349813
relation.isAuthorOfPublication.latestForDiscovery462852fa-ba94-4430-a4f9-ba1a1a22e130

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