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Cd(II) coordination compounds as heterogeneous catalysts for microwave-assisted peroxidative oxidation of toluene and 1-phenylethanol

2020-06-14Journal article Restricted access
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dc.contributor.authorSutradhar, Manas
dc.contributor.authorRoy Barman, Tannistha
dc.contributor.authorAlegria, Elisabete
dc.contributor.authorLapa, Hugo M.
dc.contributor.authorGuedes Da Silva, M. Fátima C.
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2020-06-15T15:42:56Z
dc.date.available2020-06-15T15:42:56Z
dc.date.issued2020-06-14
dc.description.abstractThe aroylhydrazone Schiff bases 2-hydroxy(2-hydroxybenzylidene)benzohydrazide (H2L1) and 2-amino(2hydroxybenzylidene)benzohydrazide (H2L2) have been used to synthesize the new Cd(II) coordination polymer [Cd(m-1kONO0:2kO:3kO00-L1)(DMF)]n (1) and the dinuclear complex [Cd(1kONO0:2kO-HL2)(kOO0Ac)]2 2DMF (2). Both 1 and 2 have been characterized by elemental analysis, FT-IR and single crystal X-ray diffraction analysis. The catalytic performances of 1 and 2 were evaluated towards the microwave (MW) assisted peroxidative oxidation (with tert-butylhydroperoxide, TBHP) of toluene and 1-phenylethanol under heterogeneous conditions. The MW-assisted peroxidative oxidation of toluene by a Cd(II) catalytic system is reported for the first time. At 50 1C, the 2/TBHP/MW catalytic system shows good activity for toluene oxidation with a total (benzaldehyde + benzyl alcohol) product yield of 49% in 1 h, in the absence of any additives. In the case of neat solvent-free peroxidative oxidation of 1-phenylethanol the 1/TBHP/MW catalytic system resulted in 24% total yield of acetophenone under optimized conditions. After the catalytic reactions, both 1 and 2 were successfully recovered and reused.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationSUTRADHAR, Manas; [et al] – Cd(II) coordination compounds as heterogeneous catalysts for microwave-assisted peroxidative oxidation of toluene and 1-phenylethanol. New Journal of Chemistry. ISSN 1144-0546. Vol. 44, N.º 22 (2020), pp. 9163–9171pt_PT
dc.identifier.doi10.1039/d0nj01408gpt_PT
dc.identifier.issn1144-0546
dc.identifier.urihttp://hdl.handle.net/10400.21/11852
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherRoyal Society of Chemistrypt_PT
dc.relationUIDB/00100/2020 - FCTpt_PT
dc.relationPTDC/QUI-QIN/29778/2017 - FCTpt_PT
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlepdf/2020/nj/d0nj01408gpt_PT
dc.subjectCoordination polymerpt_PT
dc.subjectDinuclear complexpt_PT
dc.subjectPeroxidative oxidationpt_PT
dc.subjectCatalytic systempt_PT
dc.titleCd(II) coordination compounds as heterogeneous catalysts for microwave-assisted peroxidative oxidation of toluene and 1-phenylethanolpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage9171pt_PT
oaire.citation.issue22pt_PT
oaire.citation.startPage9163pt_PT
oaire.citation.titleNew Journal of Chemistrypt_PT
oaire.citation.volume44pt_PT
person.familyNameSutradhar
person.familyNameRoy Barman
person.familyNameAlegria
person.familyNameGuedes da Silva
person.familyNamePombeiro
person.givenNameManas
person.givenNameTannistha
person.givenNameElisabete
person.givenNameM. Fátima C.
person.givenNameArmando
person.identifier863180
person.identifier863202
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person.identifier.orcid0000-0001-8323-888X
person.identifier.ridM-4089-2013
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person.identifier.scopus-author-id14053084900
person.identifier.scopus-author-id36167317100
person.identifier.scopus-author-id8315848300
person.identifier.scopus-author-id6701761571
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspt_PT
rcaap.typearticlept_PT
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