Repository logo
 
Publication

Trits(Pyrazol-1-YL)methane metal complexes for catalytic mild oxidative functionalizations of alkanes, alkanes and ketones

2014-04Journal article Restricted access
Simple item page
dc.contributor.authorMartins, Luisa
dc.contributor.authorPombeiro, Armando
dc.date.accessioned2015-08-24T14:45:55Z
dc.date.available2015-08-24T14:45:55Z
dc.date.issued2014-04
dc.description.abstractThis work concerns recent advances (since 2005) in the oxidative functionalization of alkanes, alkenes and ketones, under mild conditions, catalyzed by homoscorpionate tris(pyrazol-1-yl)methane metal complexes. The main types of such homogeneous or supported catalysts are classified, and the critical analysis of the most efficient catalytic systems in the different reactions is presented. These reactions include the mild oxidation of alkanes (typically cyclohexane as a model substrate) with hydrogen peroxide (into alkyl hydroperoxides, alcohols, and ketones), the hydrocarboxylation of gaseous alkanes (with carbon monoxide and potassium peroxodisulfate) into the corresponding Cn+1 carboxylic acids, as well as the epoxidation of alkenes and the Baeyer-Villiger oxidation of linear and cyclic ketones with hydrogen peroxide into the corresponding esters and lactones. Effects of various reaction parameters are highlighted and the preferable requirements for a prospective homogeneous or supported C-scorpionate-M-based catalyst in oxidative transformations of those substrates are identified. (C) 2014 Elsevier B.V. All rights reserved.por
dc.identifier.citationMARTINS, Luísa Margarida; POMBEIRO, Armando J. L. – Trits(Pyrazol-1-YL)Methane metal complexes for catalytic mild oxidative functionalizations of Alkanes, Alkanes and Ketones. Coordination Chemistry Reviews. ISSN: 0010-8545. Vol. 62 (2014), pp. 74-88por
dc.identifier.doi10.1016/j.ccr.2014.01.013
dc.identifier.issn0010-8545
dc.identifier.issn1873-3840
dc.identifier.urihttp://hdl.handle.net/10400.21/4968
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevier Science SApor
dc.subjectC-scorpionatepor
dc.subjectTris(pyrazol-1-yl)methanepor
dc.subjectOxidationpor
dc.subjectOxidative Functionalizationpor
dc.subjectHomogeneous Catalysispor
dc.subjectSupported Catalysispor
dc.titleTrits(Pyrazol-1-YL)methane metal complexes for catalytic mild oxidative functionalizations of alkanes, alkanes and ketonespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage88por
oaire.citation.startPage74por
oaire.citation.titleCoordination Chemistry Reviewspor
oaire.citation.volume265por
person.familyNameMartins
person.familyNamePombeiro
person.givenNameLuisa
person.givenNameArmando
person.identifier637885
person.identifier.ciencia-idE218-E297-A4EA
person.identifier.ciencia-id8311-38FA-CEFB
person.identifier.orcid0000-0002-5403-9352
person.identifier.orcid0000-0001-8323-888X
person.identifier.ridG-6210-2011
person.identifier.ridI-5945-2012
person.identifier.scopus-author-id8650947800
person.identifier.scopus-author-id7006067269
rcaap.rightsclosedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication8ed70b09-b4d3-4a5d-9f75-12b13a332204
relation.isAuthorOfPublication6d18ff2e-5c33-4010-b1e7-964c72349813
relation.isAuthorOfPublication.latestForDiscovery6d18ff2e-5c33-4010-b1e7-964c72349813

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
Tris(pyrazol-1-yl).pdf
Size:
3.25 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

ISEL - Eng. Quim. Biol. - Artigos