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Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones

2016-03Journal article Restricted access
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dc.contributor.authorMoreno Montoya, Carmen Alicia
dc.contributor.authorGomez, Clara F.
dc.contributor.authorPaninho, Ana B.
dc.contributor.authorNunes, Ana V. M.
dc.contributor.authorMahmudov, Kamran
dc.contributor.authorNajdanovic-Visak, Vesna
dc.contributor.authorMartins, Luisa
dc.contributor.authorGuedes Da Silva, M. Fátima C.
dc.contributor.authorPombeiro, Armando
dc.contributor.authorNunes Da Ponte, Manuel
dc.date.accessioned2019-02-26T10:08:13Z
dc.date.available2019-02-26T10:08:13Z
dc.date.issued2016-03
dc.description.abstractZinc(II) complexes of arylhydrazones of beta-diketones (AHBD) were used for the first time as catalysts combined with tetrabutylammonium bromide (TBABr), in the coupling reaction between CO2 and epoxides. The influence of pressure and temperature on cyclic carbonate formation was investigated, as well as the catalytic activity toward different substrates (e.g. styrene oxide, propylene oxide and cyclohexene oxide). The molar ratio between metal complex and TBABr was determined for maximum catalytic activity.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.citationMONTOYA, Carmen A.; [et al] – Cyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketones. Journal of Catalysis. ISSN 0021-9517. Vol. 335 (2016), pp. 135-140pt_PT
dc.identifier.doi10.1016/j.jcat.2015.12.027pt_PT
dc.identifier.issn0021-9517
dc.identifier.issn1090-2694
dc.identifier.urihttp://hdl.handle.net/10400.21/9590
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherElsevierpt_PT
dc.relationUID/QUI/0100/2013 - FCT-MCTESpt_PT
dc.relationIF/01374/2014 - FCTpt_PT
dc.relationELECTROCHEMICAL TRANSFORMATION OF CO2 IN ADVANCED ELECTROLYTIC SYSTEMS: ROUTES TO VALUABLE PRODUCTS
dc.relationNMR Net - National Facility for Nuclear Magnetic Resonance: from Molecular Structure and Dynamics to Protein Function, Cell Physiology, and Metabolomics
dc.relation.publisherversionhttps://ac.els-cdn.com/S002195171600004X/1-s2.0-S002195171600004X-main.pdf?_tid=39726281-9456-4e66-b058-b81abbfc2bae&acdnat=1551175539_d12bad683db8d9a27a0ab80caa6f869dpt_PT
dc.subjectCarbon dioxidept_PT
dc.subjectEpoxidept_PT
dc.subjectStyrene carbonatept_PT
dc.subjectCyclic carbonatespt_PT
dc.subjectZincpt_PT
dc.subjectArylhydrazone of B-diketonespt_PT
dc.titleCyclic carbonate synthesis from CO2 and epoxides using zinc(II) complexes of arylhydrazones of beta-diketonespt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardTitleELECTROCHEMICAL TRANSFORMATION OF CO2 IN ADVANCED ELECTROLYTIC SYSTEMS: ROUTES TO VALUABLE PRODUCTS
oaire.awardTitleNMR Net - National Facility for Nuclear Magnetic Resonance: from Molecular Structure and Dynamics to Protein Function, Cell Physiology, and Metabolomics
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FQUI%2F50006%2F2013/PT
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oaire.citation.endPage140pt_PT
oaire.citation.startPage135pt_PT
oaire.citation.titleJournal of Catalysispt_PT
oaire.citation.volume335pt_PT
oaire.fundingStream5876
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person.familyNameMoreno Montoya
person.familyNameMahmudov
person.familyNameNajdanovic-Visak
person.familyNameMartins
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person.givenNameCarmen Alicia
person.givenNameKamran
person.givenNameVesna
person.givenNameLuisa
person.givenNameM. Fátima C.
person.givenNameArmando
person.givenNameManuel
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project.funder.nameFundação para a Ciência e a Tecnologia
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project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsclosedAccesspt_PT
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