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Solution enthalpies of hydroxylic compounds

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Resumo(s)

Solution enthalpies of adamantan-1-ol, 2-methyl- butan-2-ol, and 3-methylbutan-1-ol have been measured at 298.15 K, in a set of 16 protogenic and non-protogenic solvents. The identification and quantification of solvent effects on the solution processes under study were performed using quantitative-structure property relationships. The results are discussed in terms of solute-solvent-solvent interactions and also in terms of the influence of compound's size and position of its hydroxyl group.

Descrição

Palavras-chave

QSPR Solution enthalpy Solvent effects Adamantan Methylbutan Methylbutan Solvatochromic Solvent Solvation Scale Bromodamantane Derivatives Solvolysis Models

Contexto Educativo

Citação

REIS, M.; MOREIRA, L.; NUNES, N.; LEITÃO, Rùben Elvas; MARTINS, F. - Solution enthalpies of hydroxylic compounds. Journal of Thermal Analysis and Calorimetry. 2012; 2 (108).

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Fascículo

Editora

Springer

Licença CC