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N2O-Free single-pot conversion of cyclohexane to adipic acid catalysed by an iron(II) scorpionate complex

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The highly efficient eco-friendly synthesis of adipic acid (96% yield, 98% selectivity, TONs up to 1.8 × 103) directly from cyclohexane is achieved by using ozone and [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) in a solvent-, heating-, radiation- and N2O-free new protocol.

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RIBEIRO, A. P. C.; MARTINS, L. M. D. R. S.; POMBEIRO, A. J. L. – N2O-Free single-pot conversion of cyclohexane to adipic acid catalysed by an iron(II) scorpionate complex . Green Chemistry. Vol. 19, N.º 6 (2017), pp.1499-1501

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Royal Society of Chemistry

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