Browsing by Issue Date, starting with "2020-06-11"
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- Nugget formation and mechanical behaviour of friction stir welds of three dissimilar aluminum alloysPublication . Manuel, Neves; Galvão, Ivan; Leal, Rui; Costa, José D.; Loureiro, AltinoThe aim of this research was to investigate the influence of the properties of the base materials and welding speed on the morphology and mechanical behavior of the friction stir welds of three dissimilar aluminum alloys in a T-joint configuration. The base materials were the AA2017-T4, AA5083-H111, and AA6082-T6 alloys in 3 mm-thick sheets. The AA6082-T6 alloy was the stringer, and the other alloys were located either on the advancing or retreating sides of the skin. All the T-joint welds were produced with a constant tool rotation speed but with different welding speeds. The microstructures of the welds were analyzed using optical microscopy, scanning electron microscopy with energy dispersive spectroscopy, and the electron backscatter diffraction technique. The mechanical properties were assessed according to micro-hardness, tensile, and fatigue testing. Good quality welds of the three dissimilar aluminum alloys could be achieved with friction stir welding, but a high ratio between the tool’s rotational and traverse speeds was required. The welding speed influenced the weld morphology and fatigue strength. The positioning of the skin materials influenced the nugget morphology and the mechanical behavior of the joints. The joints in which the AA2017 alloy was positioned on the advancing side presented the best tensile properties and fatigue strength.
- Nugget formation and mechanical behaviour of friction stir welds of three dissimilar aluminum alloysPublication . Neves, Manuel; Galvão, Ivan; Leal, Rui; Costa, José D.; Loureiro, AltinoThe aim of this research was to investigate the influence of the properties of the base materials and welding speed on the morphology and mechanical behavior of the friction stir welds of three dissimilar aluminum alloys in a T-joint configuration. The base materials were the AA2017-T4, AA5083-H111, and AA6082-T6 alloys in 3 mm-thick sheets. The AA6082-T6 alloy was the stringer, and the other alloys were located either on the advancing or retreating sides of the skin. All the T-joint welds were produced with a constant tool rotation speed but with different welding speeds. The microstructures of the welds were analyzed using optical microscopy, scanning electron microscopy with energy dispersive spectroscopy, and the electron backscatter diffraction technique. The mechanical properties were assessed according to micro-hardness, tensile, and fatigue testing. Good quality welds of the three dissimilar aluminum alloys could be achieved with friction stir welding, but a high ratio between the tool's rotational and traverse speeds was required. The welding speed influenced the weld morphology and fatigue strength. The positioning of the skin materials influenced the nugget morphology and the mechanical behavior of the joints. The joints in which the AA2017 alloy was positioned on the advancing side presented the best tensile properties and fatigue strength.
- A review on bio-based catalysts (immobilized enzymes) used for biodiesel productionPublication . Santos, Samuel; Puna, Jaime; Gomes, JoãoThe continuous increase of the world's population results in an increased demand for energy drastically from the industrial and domestic sectors as well. Moreover, the current public awareness regarding issues such as pollution and overuse of petroleum fuel has resulted in the development of research approaches concerning alternative renewable energy sources. Amongst the various options for renewable energies used in transportation systems, biodiesel is considered the most suitable replacement for fossil-based diesel. In what concerns the industrial application for biodiesel production, homogeneous catalysts such as sodium hydroxide, potassium hydroxide, sulfuric acid, and hydrochloric acid are usually selected, but their removal after reaction could prove to be rather complex and sometimes polluting, resulting in increases on the production costs. Therefore, there is an open field for research on new catalysts regarding biodiesel production, which can comprise heterogeneous catalysts. Apart from that, there are other alternatives to these chemical catalysts. Enzymatic catalysts have also been used in biodiesel production by employing lipases as biocatalysts. For economic reasons, and reusability and recycling, the lipases urged to be immobilized on suitable supports, thus the concept of heterogeneous biocatalysis comes in existence. Just like other heterogeneous catalytic materials, this one also presents similar issues with inefficiency and mass-transfer limitations. A solution to overcome the said limitations can be to consider the use of nanostructures to support enzyme immobilization, thus obtaining new heterogeneous biocatalysts. This review mainly focuses on the application of enzymatic catalysts as well as nano(bio)catalysts in transesterification reaction and their multiple methods of synthesis.