Browsing by Author "Brogueira, P."
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- Conducting indium oxide films on plastic substrates by plasma enhanced reactive thermal evaporationPublication . Vygranenko, Yuri; Fernandes, Miguel; Vieira, Manuela; Lavareda, Guilherme; CARVALHO, CARLOS; Brogueira, P.; Amaral, AnaThis work reports on low temperature deposition of conducing indium oxide films by a radio-frequency plasma enhanced reactive thermal evaporation (rf-PERTE) technique. The films were deposited on polyethylene terephthalate (PET) without intentional heating of the substrate and at elevated temperatures up to 150 degrees C. The material stoichiometry was accurately controlled by adjusting deposition conditions including the oxygen flow, process pressure, pumping speed, and RF-power. Besides, fine turning of the critical deposition parameters during the deposition was implemented by measuring the variation of film conductance in-situ. The film morphology was analyzed by scanning electron microscopy. Hall effect measurements were also performed to determine the relation between the deposition conditions and the electrical properties of the films. A resistivity of 4 x 10(-4) Omega-cm was reached under optimized deposition conditions. A 250 nm-thick coating with 16 Omega/sq sheet resistance shows an 82% peak value of transmittance in the visible spectral range.
- Electrical, optical and photoconductive properties of Sn-doped indium sulfofluoride thin filmsPublication . Vygranenko, Yuri; Fernandes, M.; Vieira, Manuela; Lavareda, G.; Carvalho, C. Nunes De; Brogueira, P.; Amaral, A.; Barradas, N. P.; Alves, E.This work reports on undoped and Sn-doped indium sulfofluoride thin-films deposited by radio-frequency plasma-enhanced reactive thermal evaporation. The deposition was performed evaporating pure indium or indium-tin alloy in SF6 plasma at substrate temperatures ranging from 373 to 423 K. Rutherford backscattering analysis and secondary-ion mass spectrometry were used to determine the chemical composition of the films. The film characterization includes electrical, optical, and photoconductivity measurements. The resistivity of undoped material varies in a wide range of 1 G Omega-cm to 2 T Omega-cm depending on deposition conditions. Sn doping leads to a decrease in the resistance down to 8 M Omega-cm. The films are highly transparent in the visible-infrared region due to an indirect bandgap of 2.7-3 eV. Moreover, the doped material is highly photosensitive in the blue -UV region. Photoconductivity kinetics under various excitation conditions was also studied. The synthesized material is a promising candidate for a buffer layer in chalcogenide-based solar cells.
- Espirais e Hélices - Do Polímero mais abundante da naturezaPublication . Godinho, M. H.; Canejo, João; Brogueira, P.; Teixeira, PauloA celulose é o polímero renovável mais abundante do mundo. É o principal constituinte das paredes celulares das plantas, as quais constituem a sua principal fonte.
- From wrinkly elastomers to Janus particles to Janus fibresPublication . Trindade, A. C.; Canejo, J. P.; Patricio, Pedro; Brogueira, P.; Teixeira, Paulo; Godinho, Maria HelenaAim is to fabricate Janus objects possessing two distinct sides, through control and manipulation of uneable sub-micron scale long-lived textures in urethane/urea elastomer films, spheres and fibres. Textures are obtained by UV-irradiation of the elastomers followed by mechanical deformation or swelling in a solvent. Standard chemistry, no complex deposition techniques required. Resulting textures investigated using AFM, SEM, SALS and POM. Interpreted by assuming that each film, sphere or fibre consists of a thin, stiff surface layer (“skin”) lying atop a thicker, softer substrate (“bulk”).
- InOx thin films deposited by plasma assisted evaporation: application in light shuttersPublication . Merino, E. G.; Almeida, Pedro L.; Carvalho, Carlos Nunes de; Brogueira, P.; Amaral, A.; Lavareda, GuilhermeAn integration of undoped InOx and commercial ITO thin films into laboratory assembled light shutter devices is made. Accordingly, undoped transparent conductive InOx thin films, about 100 nm thick, are deposited by radiofrequency plasma enhanced reactive thermal evaporation (rf-PERTE) of indium teardrops with no intentional heating of the glass substrates. The process of deposition occurs at very low deposition rates (0.1-0.3 nm/s) to establish an optimized reaction between the oxygen plasma and the metal vapor. These films show the following main characteristics: transparency of 87% (wavelength, lambda = 632.8 nm) and sheet resistance of 52 Omega/sq; while on commercial ITO films the transparency was of 92% and sheet resistance of 83 Omega/sq. The InOx thin film surface characterized by AFM shows a uniform grain texture with a root mean square surface roughness of Rq similar to 2.276 nm. In contrast, commercial ITO topography is characterized by two regions: one smoother with Rq similar to 0.973 nm and one with big grains (Rq similar to 3.617 nm). For the shutters assembled using commercial ITO, the light transmission coefficient (Tr) reaches the highest value (Tr-max) of 89% and the lowest (Tr-min) of 1.3% [13], while for the InOx shutters these values are 80.1% and 3.2%, respectively. Regarding the electric field required to achieve 90% of the maximum transmission in the ON state (E-on), the one presented by the devices assembled with commercial ITO coated glasses is 2.41 V/mu m while the one presented by the devices assembled with InOx coated glasses is smaller, 1.77 V/mu m. These results corroborate the device quality that depends on the base materials and fabrication process used. (C) 2014 Elsevier Ltd. All rights reserved.
- Structural, electrical and magnetic studies of Co:SnO2 and (Co,Mo):SnO2 films prepared by pulsed laser depositionPublication . Dalui, S.; Rout, S.; Silvestre, António Jorge; Lavareda, G.; Pereira, L. C. J.; Brogueira, P.; Conde, O.Here we report on the structural, optical, electrical and magnetic properties of Co-doped and (Co,Mo)-codoped SnO2 thin films deposited on r-cut sapphire substrates by pulsed laser deposition. Substrate temperature during deposition was kept at 500 degrees C. X-ray diffraction analysis showed that the undoped and doped films are crystalline with predominant orientation along the [1 0 1] direction regardless of the doping concentration and doping element. Optical studies revealed that the presence of Mo reverts the blue shift trend observed for the Co-doped films. For the Co and Mo doping concentrations studied, the incorporation of Mo did not contribute to increase the conductivity of the films or to enhance the ferromagnetic order of the Co-doped films. (C) 2012 Elsevier B.V. All rights reserved.