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Orientador(es)
Resumo(s)
5-Monocyclopentadienyliron(II)/ruthenium(II) complexes of the general formula [M(5-C5H5)(PP)(L1)][PF6] {M = Fe, PP = dppe; M = Ru, PP = dppe or 2PPh3; L1 = 5-[3-(thiophen-2-yl)benzo[c]thiophenyl]thiophene-2-carbonitrile} have been synthesized and studied to evaluate their molecular quadratic hyperpolarizabilities. The compounds were fully characterized by NMR, FTIR and UV/Vis spectroscopy and their electrochemical behaviour studied by cyclic voltammetry. Quadratic hyperpolarizabilities () were determined by hyper-Rayleigh scattering measurements at a fundamental wavelength of 1500 nm. Density functional theory calculations were employed to rationalize the second-order non-linear optical properties of these complexes.
Descrição
Palavras-chave
Ruthenium Iron Sulfur heterocycles Nonlinear Optics Hyperpolarizabilities
Contexto Educativo
Citação
SILVA, Tiago J. L.; [et al] - Benzo[c]thiophene Chromophores Linked to Cationic Fe and Ru Derivatives for NLO Materials: Synthesis Characterization and Quadratic Hyperpolarizabilities. European Journal of Inorganic Chemistry. Vol. 2013, nr. 20 (2013), p. 3506-3517.
Editora
WIiley-V C H Verlag GMBH