Pinto, LuísGlória, PauloGomes, MárioRzepa, Henry S.Prabhakar, SundaresanLobo, Ana M.2012-01-062012-01-062009-03Pinto L, Glória P, Gomes M, Rzepa HS, Prabhakar S, Lobo AM. A dramatic effect of double bond configuration in N-oxy-3-aza Cope rearrangements: a simple synthesis of functionalised allenes. Tetrahedron Lett. 2009;50:3446-9.0040-4039http://hdl.handle.net/10400.21/1016The first examples of low temperature N-oxy-3-aza Cope rearrangements, leading to functionalised allenes are described, where the Z-configuration of the enaminic double bond in the rearranging system proves critical.engChemistry3-Aza Cope RearrangementsHydroxylaminesEnaminesAllenesConfigurationIntermediatesTransition statesjournal article